{"id":"W4407041635","doi":"10.1021/jacs.4c16123","title":"Photolytic and Thermal Reactions of [C<sub>6</sub>H<sub>4</sub>(PPh<sub>2</sub>)<sub>2</sub>(μ-N<sub>2</sub>)] and Its Lewis Acid Adducts: N–N Bond Cleavage and Liberation of N<sub>2</sub>","year":2025,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Deutsche Forschungsgemeinschaft","keywords":"Chemistry; Adduct; Lewis acids and bases; Bond cleavage; Phosphine; Thermal decomposition; Acceptor; Frustrated Lewis pair; Medicinal chemistry; Photodissociation; Photochemistry; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009860181,0.0002907208,0.0001134507,0.00007550417,0.0001271966,0.0001579362,0.0002148361,0.0002554912,0.001723524],"category_scores_gemma":[0.0001463245,0.0001471566,0.00009980747,0.00007438933,0.0001850995,0.0002563811,0.0002155205,0.0003205583,0.000219174],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001998686,"about_ca_system_score_gemma":0.0001630901,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004447321,"about_ca_topic_score_gemma":0.001197629,"domain_scores_codex":[0.9999279,0.00001034922,0.00000311414,0.00001807511,0.0000208705,0.00001968007],"domain_scores_gemma":[0.9999634,0.000006653563,0.00001410173,0.000005331456,0.000004993825,0.000005543256],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009332253,0.00001450778,0.00006109487,0.00006740379,0.000005391277,0.00003952761,0.0000305927,0.0002059064,0.9970058,0.000302303,0.0001002277,0.002074044],"study_design_scores_gemma":[0.000004077107,0.00009234509,0.0002724173,0.000001828511,0.000003581452,0.00005426716,0.000009727125,0.0003945256,0.9982308,0.00003676476,0.000896092,0.00000373348],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9845961,0.001026349,0.005523749,0.00007350599,0.00006993058,0.00005792707,0.0001272583,0.00008931327,0.008435787],"genre_scores_gemma":[0.9928259,0.0004383666,0.003058929,0.00004142512,0.000008174595,0.00002870436,0.00006950076,0.00001831939,0.0035107],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001723524,"threshold_uncertainty_score":0.005765796,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006229553793603914,"score_gpt":0.2185803593700459,"score_spread":0.212350805576442,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}