{"id":"W4407139047","doi":"10.1080/00958972.2025.2453065","title":"Examination of metal-π interactions in the coordination chemistry of heavy alkaline earth metal tetraarylborates","year":2025,"lang":"en","type":"article","venue":"Journal of Coordination Chemistry","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Alkaline earth metal; Coordination complex; Metal; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001088628,0.0001654488,0.0002195053,0.0001451045,0.000396873,0.0002393331,0.0002523339,0.0001331162,0.001760725],"category_scores_gemma":[0.0001611899,0.0001542577,0.00008367434,0.0001307833,0.0002712423,0.0001471274,0.0002024037,0.0001976153,0.0001578623],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002615115,"about_ca_system_score_gemma":0.0001776379,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001467615,"about_ca_topic_score_gemma":0.001800001,"domain_scores_codex":[0.9999449,0.00001042196,0.000003247006,0.000009810488,0.0000150182,0.00001664721],"domain_scores_gemma":[0.9999598,0.00001801202,0.000007691545,0.000003068462,0.000004702312,0.000006721095],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008503845,0.0000753252,0.002639821,0.000235139,0.0000342109,0.0003874284,0.0002894513,0.009735878,0.9697053,0.009145321,0.0002897424,0.006612023],"study_design_scores_gemma":[0.0002018411,0.00105092,0.01066562,0.00003160061,0.00007658183,0.0005445468,0.0004379324,0.07850932,0.9011687,0.00418575,0.003074466,0.00005277964],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9977891,0.0001380463,0.0006371137,0.00002336331,0.000001826298,0.00000336835,0.00001574275,0.00002331932,0.001368086],"genre_scores_gemma":[0.9994191,0.00008059957,0.0002616619,0.000005873048,7.276254e-7,0.000003863787,0.0000190185,0.000004635465,0.0002046162],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001760725,"threshold_uncertainty_score":0.005890191,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01160745272946073,"score_gpt":0.2784294998577405,"score_spread":0.2668220471282798,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}