{"id":"W4407172629","doi":"10.1016/j.jinorgbio.2025.112851","title":"RP-HPLC reveals the L-cysteine induced degradation of phenylmercuric acetate","year":2025,"lang":"en","type":"article","venue":"Journal of Inorganic Biochemistry","topic":"Porphyrin Metabolism and Disorders","field":"Biochemistry, Genetics and Molecular Biology","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"University of Calgary","keywords":"Chemistry; Degradation (telecommunications); High-performance liquid chromatography; Cysteine; Chromatography; Biochemistry; Enzyme","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000436411,0.0001480747,0.0002455649,0.00005453875,0.00005504279,0.00001586815,0.000449798,0.0001739453,0.00002095659],"category_scores_gemma":[0.0004052465,0.00010544,0.0001618186,0.000285208,0.00008628397,0.000006833158,0.0001023114,0.0001962008,0.000001442456],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001571844,"about_ca_system_score_gemma":0.0002912857,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000627959,"about_ca_topic_score_gemma":0.000001428778,"domain_scores_codex":[0.9988809,0.00005901876,0.0005551853,0.0001538435,0.0001895935,0.0001614308],"domain_scores_gemma":[0.9987246,0.00002305321,0.0005413411,0.000374171,0.0002811619,0.00005569487],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007722586,0.00006574676,0.001417586,0.00006839231,0.0001248821,0.000001410031,0.00002059642,0.000003498747,0.9916881,0.00005173964,0.004857718,0.001623066],"study_design_scores_gemma":[0.0007761247,0.00008237774,0.002879722,0.00005518253,0.0000953099,0.00004324432,0.0002233569,0.000002699883,0.9925737,0.0002683008,0.00289941,0.0001005061],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9915418,0.005781961,0.0003930308,0.0006813764,0.0002391414,0.00007268819,0.000008034842,0.000003119389,0.001278819],"genre_scores_gemma":[0.9969241,0.0006387141,0.0003099487,0.0003318195,0.0001947707,0.000001835511,0.00001531159,0.00001106065,0.00157241],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005382301,"threshold_uncertainty_score":0.4299717,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006904533137494722,"score_gpt":0.243954418981201,"score_spread":0.2370498858437063,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}