{"id":"W4407257973","doi":"10.1002/aic.18764","title":"Sequential hydrogenation enhanced by bidirectional hydrogen spillover over cascade catalyst","year":2025,"lang":"en","type":"article","venue":"AIChE Journal","topic":"Nanomaterials for catalytic reactions","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Science Foundation of Shandong Province; National Natural Science Foundation of China; Jinan Science and Technology Bureau","keywords":"Catalysis; Cascade; Hydrogen spillover; Hydrogen; Chemistry; Spillover effect; Cascade reaction; Materials science; Combinatorial chemistry; Metal; Chemical engineering; Nanotechnology; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002463782,0.0002108088,0.0002312048,0.0001549305,0.0003042785,0.0001431454,0.0002518258,0.0002056587,0.003277526],"category_scores_gemma":[0.0001049493,0.0002048645,0.0002160685,0.0002504775,0.00006181437,0.0003618488,0.00006734699,0.0003484763,0.0001663885],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005526768,"about_ca_system_score_gemma":0.0002456881,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001392373,"about_ca_topic_score_gemma":0.000016433,"domain_scores_codex":[0.9984654,0.00002648261,0.0005088841,0.0002730284,0.0003998833,0.0003262778],"domain_scores_gemma":[0.9991766,0.00005309369,0.0002660995,0.0002646706,0.0001076201,0.0001319173],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003702414,0.00008283669,0.0002971406,0.00001991598,0.0002863834,0.000008667276,0.0000440653,0.00002902978,0.9718533,0.00004709247,0.02663165,0.0006628744],"study_design_scores_gemma":[0.000755641,0.000007830622,0.0001331491,0.00004246659,0.0001319123,0.0001944548,0.0000287189,0.00009079331,0.9210825,0.0004600859,0.07689209,0.0001803825],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9742709,0.0003008763,0.000613831,0.0002940698,0.0009531944,0.00005764252,0.00008140026,0.00008406791,0.02334405],"genre_scores_gemma":[0.9818511,0.00009677983,0.00006823199,0.0001518367,0.0005896267,0.0000138868,0.0001788235,0.00002844602,0.01702129],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05077085,"threshold_uncertainty_score":0.9976336,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00722542004123879,"score_gpt":0.2574815679093824,"score_spread":0.2502561478681436,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}