{"id":"W4407333102","doi":"10.1007/s10008-025-06221-4","title":"An exploratory kinetic analysis of photoelectrochemical oxygen evolution on hematite","year":2025,"lang":"en","type":"article","venue":"Journal of Solid State Electrochemistry","topic":"Iron oxide chemistry and applications","field":"Energy","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"McGill University","keywords":"Photocurrent; Kinetics; Electron transfer; Oxygen evolution; Analytical Chemistry (journal); Proton; Materials science; Chemistry; Electrochemistry; Physical chemistry; Physics; Electrode","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002375743,0.0002195922,0.0005514602,0.0002811937,0.00006874747,0.00001837078,0.0004317065,0.0001460982,0.0001094526],"category_scores_gemma":[0.00009511929,0.0002146559,0.0003252291,0.001277127,0.00008054584,0.0001105792,0.0000221928,0.000448272,0.000002938496],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000299246,"about_ca_system_score_gemma":0.0002562203,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003888512,"about_ca_topic_score_gemma":0.000006312439,"domain_scores_codex":[0.9982092,0.00004131244,0.0008309957,0.0002500232,0.0003404187,0.0003279971],"domain_scores_gemma":[0.9983112,0.00009538892,0.0005985923,0.0004427906,0.0004077316,0.0001442542],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002260121,0.0003298663,0.0001065126,0.00008602533,0.0008158991,0.000004081401,0.0001079541,0.003642865,0.99324,0.0006096723,0.0006697847,0.0001613111],"study_design_scores_gemma":[0.0004215418,0.0001252591,0.0003870113,0.0000704811,0.0006270556,0.00001176213,0.0001389301,0.001187405,0.9936856,0.002589053,0.0005928374,0.0001630457],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9899352,0.0003808334,0.006637022,0.0000909996,0.00002584495,0.0000515428,0.00001916355,0.00002721611,0.00283213],"genre_scores_gemma":[0.9988253,0.00008839266,0.0003157116,0.00009479172,0.00009117756,0.0000129591,0.00004668752,0.00001651972,0.0005084265],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008890086,"threshold_uncertainty_score":0.8753412,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005692487079732206,"score_gpt":0.2653698665515155,"score_spread":0.2596773794717833,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}