{"id":"W4407349173","doi":"10.1002/chem.202404777","title":"Aluminum Photosensitizers on Trial: Synthesis, Crystal Structures, Photophysical and Photobiological Properties of Tris(Dipyrrinato)Aluminum(III) Complexes with Long‐Lived Triplet States","year":2025,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Trinity College","funders":"Research Ireland; HORIZON EUROPE Marie Sklodowska-Curie Actions; Higher Education Authority; Institute for Advanced Study, Technische Universität München; Science Foundation Ireland; Technische Universität München; European Commission","keywords":"Singlet oxygen; Photochemistry; Chemistry; Homoleptic; Density functional theory; Photoexcitation; Excited state; Oxygen; Metal; Computational chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007954305,0.0001320748,0.0001235727,0.0001403888,0.0001173703,0.0002356271,0.0002853492,0.0001539449,0.001653493],"category_scores_gemma":[0.0001536405,0.00009433551,0.0001040514,0.0001435387,0.00009402425,0.0001030681,0.0001305113,0.00020503,0.000183793],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003144502,"about_ca_system_score_gemma":0.0001410208,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008095183,"about_ca_topic_score_gemma":0.0008598607,"domain_scores_codex":[0.9999311,0.000007665007,0.000004902723,0.0000165237,0.00002491934,0.00001492709],"domain_scores_gemma":[0.9999368,0.000009883599,0.00001790692,0.000006979194,0.00001527314,0.00001317534],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001703192,0.0000431795,0.0002001104,0.00007045744,0.000007665232,0.00003257977,0.00001919929,0.0002464585,0.995477,0.0001089884,0.0001587461,0.00346527],"study_design_scores_gemma":[0.00001187981,0.0002346412,0.0007891191,0.000002667425,0.000009186847,0.00004908708,0.000006951705,0.0007847914,0.996712,0.000009675726,0.001388231,0.000001828686],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960623,0.001089587,0.0008361572,0.00004104511,0.0000103912,0.00002139848,0.0001855569,0.00007048986,0.001682957],"genre_scores_gemma":[0.9964278,0.0004400755,0.001038895,0.00001676877,0.000002583876,0.00001248458,0.0002247897,0.00002024242,0.001816232],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001653493,"threshold_uncertainty_score":0.00553149,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02005614306648514,"score_gpt":0.2289081644765979,"score_spread":0.2088520214101128,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}