{"id":"W4407722619","doi":"10.1021/jacsau.5c00072","title":"Discovery of a Distinctive Reagent for Divergent Arene Trifluoromethylsulfinylation","year":2025,"lang":"en","type":"article","venue":"JACS Au","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Education Department of Shaanxi Province; University of Chinese Academy of Sciences; Nankai University; Chinese Academy of Sciences; Chinese University of Hong Kong; Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences; Northwest University; Natural Science Foundation of Shaanxi Province; National Natural Science Foundation of China; McGill University","keywords":"Reagent; Chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002885214,0.0003826419,0.0001418569,0.0001408664,0.000111966,0.0002218208,0.0003198046,0.0004517441,0.001886798],"category_scores_gemma":[0.0002228685,0.000149438,0.0002355478,0.00009087897,0.000239384,0.0004169983,0.0002853715,0.0007707344,0.0006209547],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002410422,"about_ca_system_score_gemma":0.0001747089,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002190645,"about_ca_topic_score_gemma":0.0004699827,"domain_scores_codex":[0.9998935,0.00001239207,0.00000569725,0.00002932091,0.00003408389,0.00002491553],"domain_scores_gemma":[0.9999138,0.00001471231,0.00003382037,0.00001029209,0.0000156465,0.00001169055],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005424623,0.00002404115,0.00007658748,0.00008368058,0.000007589083,0.0000729178,0.00002887371,0.0003406177,0.9929057,0.001680526,0.0002475343,0.004477707],"study_design_scores_gemma":[0.00001184037,0.0001349962,0.0001833302,0.000005686248,0.000004670387,0.0000928924,0.00001004403,0.001072079,0.9946845,0.0001179636,0.003676481,0.000005537358],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8662505,0.002246631,0.1148089,0.0006735131,0.0001403397,0.0002243326,0.0005939589,0.0008230967,0.01423868],"genre_scores_gemma":[0.956068,0.001480019,0.03615095,0.0001845303,0.00002945791,0.00009847662,0.0004192137,0.00007797307,0.00549138],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001886798,"threshold_uncertainty_score":0.006311953,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.09181915795024968,"score_gpt":0.4466785519771586,"score_spread":0.3548593940269089,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}