{"id":"W4407722619","doi":"10.1021/jacsau.5c00072","title":"Discovery of a Distinctive Reagent for Divergent Arene Trifluoromethylsulfinylation","year":2025,"lang":"en","type":"article","venue":"JACS Au","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Education Department of Shaanxi Province; University of Chinese Academy of Sciences; Nankai University; Chinese Academy of Sciences; Chinese University of Hong Kong; Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences; Northwest University; Natural Science Foundation of Shaanxi Province; National Natural Science Foundation of China; McGill University","keywords":"Reagent; Chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003986621,0.0001433701,0.0002410863,0.00006634484,0.0001168683,0.000008140971,0.0001929333,0.0002011836,0.0002195884],"category_scores_gemma":[0.0005362684,0.000139881,0.000127543,0.0002312303,0.0001094977,0.00006803466,0.0001222758,0.0002234717,0.000009034636],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002390759,"about_ca_system_score_gemma":0.0002124558,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004041529,"about_ca_topic_score_gemma":0.00001207948,"domain_scores_codex":[0.9989864,0.0000749074,0.0003569998,0.0002536852,0.00009565016,0.0002323416],"domain_scores_gemma":[0.9987884,0.000684987,0.0001547516,0.0002089714,0.0001103827,0.00005251186],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001263527,0.0008103066,0.03517772,0.0004979844,0.0006105807,0.000004594304,0.0006855314,0.0002547623,0.9095848,0.00750419,0.01993828,0.0236677],"study_design_scores_gemma":[0.001755008,0.00007488941,0.0131606,0.00002695417,0.0002284272,0.00000127415,0.0000984583,0.00066084,0.9315342,0.002833126,0.04948668,0.0001395503],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.980698,0.0003331818,0.007550343,0.0009865869,0.001769297,0.0005128477,0.0002895427,0.00004355223,0.0078166],"genre_scores_gemma":[0.9897795,0.00005624524,0.0003709291,0.0002074028,0.000204183,0.00009200272,0.00007831479,0.00001254653,0.009198857],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0295484,"threshold_uncertainty_score":0.5704181,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.09181915795024968,"score_gpt":0.4466785519771586,"score_spread":0.3548593940269089,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}