{"id":"W4407732980","doi":"10.1139/cjc-2024-0254","title":"Frustrated Lewis pairs reactivity across the periodic table: The 2024 Catalysis Award Lecture","year":2025,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Frustrated Lewis pair; Reactivity (psychology); Catalysis; Lewis acids and bases; Computational chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001642227,0.0006511832,0.0002374283,0.0003038412,0.001176689,0.001988311,0.0005747508,0.001761105,0.01131508],"category_scores_gemma":[0.0008999758,0.0002533457,0.0002826077,0.0002758534,0.0008928273,0.00195121,0.001525322,0.002793425,0.003069684],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.002937076,"about_ca_system_score_gemma":0.001998449,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003152524,"about_ca_topic_score_gemma":0.006493005,"domain_scores_codex":[0.9993564,0.00008639639,0.0000151184,0.00006619834,0.0002814209,0.0001944241],"domain_scores_gemma":[0.9997494,0.00002675022,0.000009118654,0.00001123945,0.00005501797,0.0001484209],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0002904306,0.0001650039,0.0004388869,0.0003024869,0.00003597453,0.0004858318,0.0003822139,0.001322684,0.01409961,0.148149,0.6349275,0.1994003],"study_design_scores_gemma":[0.00003367987,0.0001755764,0.0002732328,0.00006662748,0.000008105826,0.0001507127,0.00009921852,0.0007610603,0.005646838,0.01659483,0.9761596,0.00003051231],"study_design_candidate":"not_applicable","study_design_consensus":"not_applicable","genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.04594262,0.2179737,0.01707482,0.2515644,0.1277369,0.0002120142,0.0005444488,0.0008915174,0.3380595],"genre_scores_gemma":[0.3181576,0.09343015,0.01216557,0.02929915,0.02087736,0.0001862496,0.0005256578,0.0004015372,0.5249569],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.01131508,"threshold_uncertainty_score":0.0378527,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006088417949375948,"score_gpt":0.222086341870399,"score_spread":0.215997923921023,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}