{"id":"W4407758827","doi":"10.1039/d4gc05976j","title":"A chemoselective electrochemical birch carboxylation of pyridines","year":2025,"lang":"en","type":"article","venue":"Green Chemistry","topic":"CO2 Reduction Techniques and Catalysts","field":"Energy","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Carboxylation; Electrochemistry; Chemistry; Organic chemistry; Combinatorial chemistry; Catalysis; Electrode","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000250492,0.0005526551,0.0002864035,0.0001959211,0.0001672016,0.0002009085,0.0004586533,0.0004126606,0.001857446],"category_scores_gemma":[0.0002548122,0.0001796564,0.0001487488,0.0001901283,0.0002169566,0.0003748103,0.0003288071,0.0006431162,0.0004977565],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003394225,"about_ca_system_score_gemma":0.0003103607,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008047171,"about_ca_topic_score_gemma":0.001846571,"domain_scores_codex":[0.9997801,0.00002345004,0.00001204275,0.00005403004,0.00006345008,0.00006694024],"domain_scores_gemma":[0.9999248,0.00001472643,0.00001787112,0.000009725197,0.00001712955,0.00001568291],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004468063,0.00002032843,0.00004076871,0.0001494016,0.000006380273,0.00009090203,0.00002399573,0.0001191232,0.9925187,0.0005926327,0.0002001088,0.006192962],"study_design_scores_gemma":[0.000005679125,0.00011671,0.0002676284,0.000003176875,0.000003747092,0.0001070264,0.000007488172,0.0004274704,0.9968609,0.00003267553,0.002160452,0.000007062315],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9020769,0.01008253,0.06005852,0.0006911359,0.0003998901,0.00022375,0.0007630613,0.0009155972,0.02478854],"genre_scores_gemma":[0.9828098,0.002222558,0.008430248,0.0001511391,0.00002263776,0.00004079703,0.0001867741,0.00002579887,0.006110216],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001857446,"threshold_uncertainty_score":0.006213844,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005109769779351823,"score_gpt":0.2387643987013528,"score_spread":0.233654628922001,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}