{"id":"W4407820189","doi":"10.1002/ange.202500929","title":"Photoexcited Transition‐Metal Catalyzed Carbon‐Halogen Bond Formation","year":2025,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"University of Toronto","keywords":"Transition metal; Halogen; Catalysis; Chemistry; Carbon fibers; Halogen bond; Photochemistry; Materials science; Organic chemistry; Composite number","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001133549,0.0001990083,0.00009227829,0.0001305999,0.0001531113,0.0001711219,0.0003175836,0.000291442,0.002637977],"category_scores_gemma":[0.0001203842,0.00009956174,0.0001004161,0.0001062039,0.000208087,0.0002019986,0.0002632607,0.0002766428,0.0003059877],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003032509,"about_ca_system_score_gemma":0.0001602818,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001017812,"about_ca_topic_score_gemma":0.001694167,"domain_scores_codex":[0.9999309,0.000008188204,0.000002500867,0.000015826,0.00001871261,0.00002387131],"domain_scores_gemma":[0.9999655,0.00001073068,0.000007458726,0.000004906718,0.000006352727,0.000004990884],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009054352,0.0000427588,0.0001835637,0.0002938886,0.00001190621,0.0001576821,0.00006204187,0.0004177063,0.9841615,0.002896832,0.001654242,0.01002734],"study_design_scores_gemma":[0.00001987359,0.0001256864,0.0004558745,0.000006601281,0.000004403688,0.0001108488,0.0000156332,0.001403877,0.9918838,0.0001953987,0.005769957,0.000008080935],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9597987,0.004635625,0.01109765,0.0004830141,0.0002358675,0.00006011096,0.0003370789,0.0004216916,0.02293034],"genre_scores_gemma":[0.995382,0.0006094058,0.001681399,0.00003957086,0.000007757851,0.000007298133,0.00004475042,0.00001034111,0.002217521],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002637977,"threshold_uncertainty_score":0.008824944,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007454486113165956,"score_gpt":0.2107741813370136,"score_spread":0.2033196952238476,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}