{"id":"W4407820808","doi":"10.1039/d4qo02261k","title":"<sup> <i>t</i> </sup>BuOK-mediated selective 1,2-silacarboxylation of arylalkenes with Si–B/Si–Si/Si–Li reagents and CO<sub>2</sub>","year":2025,"lang":"en","type":"article","venue":"Organic Chemistry Frontiers","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"Natural Science Foundation of Jiangsu Province; National Natural Science Foundation of China","keywords":"Chemistry; Reagent; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002032963,0.0008771137,0.001010402,0.0000887255,0.0004040336,0.0001647447,0.0006292294,0.0009091072,0.0008413467],"category_scores_gemma":[0.0003690558,0.000925505,0.0001871776,0.0009019867,0.0005600563,0.0002573052,0.0002213849,0.000842193,0.00002047455],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005621672,"about_ca_system_score_gemma":0.0007351048,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003387394,"about_ca_topic_score_gemma":0.000008308416,"domain_scores_codex":[0.9961965,0.00003906117,0.0009057074,0.001334217,0.0006657218,0.0008587586],"domain_scores_gemma":[0.9974967,0.0001644148,0.000537166,0.001034435,0.0003314369,0.0004358846],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003463636,0.0002554733,0.02926293,0.001179087,0.0005557476,0.00002771495,0.000421036,0.00001790747,0.9530576,0.000002144292,0.01345367,0.001420335],"study_design_scores_gemma":[0.003172088,0.00003761368,0.0007249903,0.0003000762,0.0003718141,0.00004769504,0.001703982,0.0006773255,0.9893687,0.00005104778,0.002707541,0.0008371068],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9841962,0.001656309,0.0002025849,0.0003359815,0.00011522,0.0002509766,0.0002486419,0.0003639683,0.01263006],"genre_scores_gemma":[0.9951,0.000769638,0.0002037755,0.0002297588,0.0002504977,0.00003899434,0.0006765635,0.0001657656,0.00256504],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03631112,"threshold_uncertainty_score":0.9993196,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003346575772396955,"score_gpt":0.1897247911284931,"score_spread":0.1863782153560962,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}