{"id":"W4408241739","doi":"10.1002/cctc.202401941","title":"Trapping Hydrogen: Confined Catalysis for Improved Alcohol Amination Selectivity","year":2025,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Canada Foundation for Innovation; McGill University","keywords":"Selectivity; Amination; Trapping; Catalysis; Alcohol; Chemistry; Hydrogen; Heterogeneous catalysis; Photochemistry; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008264472,0.0002563491,0.0001639993,0.0001056377,0.00008942222,0.0002409032,0.0003391616,0.000324102,0.0007268726],"category_scores_gemma":[0.0001081868,0.0001636219,0.0001573987,0.00007108554,0.0002421227,0.0002901481,0.0002759387,0.0003103243,0.000278529],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002566856,"about_ca_system_score_gemma":0.0001209093,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005034647,"about_ca_topic_score_gemma":0.001025654,"domain_scores_codex":[0.9999323,0.000006353407,0.000004420309,0.00001916348,0.00001789638,0.00001990962],"domain_scores_gemma":[0.9999137,0.00001834333,0.00002891297,0.00001212236,0.00001396805,0.00001289199],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001934964,0.00001048253,0.00003807387,0.00002592782,0.000003536939,0.00003699368,0.00001243405,0.0002102281,0.9983316,0.0002235895,0.00004954784,0.00103809],"study_design_scores_gemma":[0.000007725231,0.00007214678,0.0002527959,0.00000136191,0.000004643065,0.00003104744,0.0000059944,0.002145819,0.9965634,0.00002904593,0.0008820855,0.000004075218],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9817882,0.0006838606,0.01404912,0.00006808388,0.00002845354,0.00002344205,0.00007592214,0.000277781,0.003005272],"genre_scores_gemma":[0.9950132,0.0001355581,0.003967917,0.0000233969,0.000005403375,0.00001040513,0.00002882428,0.00001429443,0.0008009596],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007268726,"threshold_uncertainty_score":0.002431631,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01198322569745376,"score_gpt":0.2660832647523992,"score_spread":0.2541000390549454,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}