{"id":"W4408319288","doi":"10.1002/9783527842971.ch1","title":"The Palladium/Norbornene‐Catalyzed Annulation Chemistry: Rapid Access to Diverse Ring Structures","year":2025,"lang":"en","type":"other","venue":"","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Annulation; Norbornene; Palladium; Catalysis; Ring (chemistry); Chemistry; Combinatorial chemistry; Organic chemistry; Copolymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009120227,0.0006138886,0.0002368696,0.0003994603,0.0002242968,0.0006252246,0.0004043949,0.0002830353,0.008363495],"category_scores_gemma":[0.00006120138,0.0002834082,0.0001611937,0.0004206139,0.0002547282,0.0006697152,0.0003935405,0.000856957,0.005012921],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000391232,"about_ca_system_score_gemma":0.000297267,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002652816,"about_ca_topic_score_gemma":0.0006162555,"domain_scores_codex":[0.9999416,0.000004202192,0.000002653676,0.00002030644,0.00002214517,0.0000091364],"domain_scores_gemma":[0.9999866,0.000002162213,0.000002819949,0.000002261235,0.000003009348,0.000003035676],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009878296,0.0001583959,0.0001337293,0.002004232,0.00002357603,0.0003387725,0.0002291722,0.002303027,0.4860421,0.07744028,0.0117353,0.4194925],"study_design_scores_gemma":[0.00001228976,0.0001759033,0.0001994525,0.0001021383,0.00001252147,0.0005164595,0.00002918546,0.0012802,0.2922198,0.003643323,0.7017887,0.00002001746],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.09631145,0.2297,0.1544652,0.001497192,0.001525705,0.0005371213,0.001597729,0.002071426,0.5122942],"genre_scores_gemma":[0.3110346,0.2793798,0.08238631,0.0005821388,0.0004462228,0.0003438329,0.001491709,0.0003662593,0.3239691],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.008363495,"threshold_uncertainty_score":0.02797866,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02347877368712615,"score_gpt":0.3074866954143869,"score_spread":0.2840079217272607,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}