{"id":"W4408323817","doi":"10.1002/anie.202503331","title":"Reactions of R<sub>3</sub>PNNPR<sub>3</sub> Species with Boranes: Classical Adducts, FLPs, and Radical Cations","year":2025,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Deutsche Forschungsgemeinschaft","keywords":"Adduct; Boranes; Chemistry; Frustrated Lewis pair; Reactivity (psychology); Lewis acids and bases; Radical ion; Medicinal chemistry; Thermal decomposition; Radical; Decomposition; Stereochemistry; Ion; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001156823,0.0002278331,0.0001152771,0.00006138778,0.0001053023,0.000128429,0.0002018646,0.0001960162,0.00224889],"category_scores_gemma":[0.0001397322,0.00008926035,0.0001098524,0.00006027828,0.0001717961,0.0002550378,0.0002130817,0.0003286616,0.0003267911],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001869593,"about_ca_system_score_gemma":0.00008622967,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002186563,"about_ca_topic_score_gemma":0.0003822075,"domain_scores_codex":[0.9999415,0.00001078514,0.000002282612,0.00001265641,0.00001697817,0.00001593313],"domain_scores_gemma":[0.9999498,0.00001129972,0.00001902945,0.000006138375,0.000005885274,0.00000780358],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001164431,0.00001173516,0.0001349851,0.0001293384,0.00001432833,0.0001079295,0.00004391002,0.0002021322,0.9968342,0.0006537765,0.0001708599,0.001580305],"study_design_scores_gemma":[0.00001097471,0.0001535614,0.0003990291,0.000004004171,0.000005791025,0.0001335634,0.00001581772,0.0004879591,0.9961519,0.00009789771,0.002534598,0.000004988882],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9908782,0.0006181688,0.003814801,0.0001094234,0.00003851775,0.00003082131,0.0001132358,0.0001066188,0.004290359],"genre_scores_gemma":[0.9955471,0.0002730098,0.001755162,0.00005031914,0.000006259974,0.00001437362,0.00008705701,0.00002187416,0.002244854],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00224889,"threshold_uncertainty_score":0.007523239,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008574962524839214,"score_gpt":0.2278699257134406,"score_spread":0.2192949631886014,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}