{"id":"W4408343063","doi":"10.1002/ange.202503331","title":"Reactions of R<sub>3</sub>PNNPR<sub>3</sub> Species with Boranes: Classical Adducts, FLPs, and Radical Cations","year":2025,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Boron Compounds in Chemistry","field":"Medicine","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Deutsche Forschungsgemeinschaft","keywords":"Boranes; Chemistry; Adduct; Organic chemistry; Stereochemistry; Boron","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001598459,0.0003137997,0.0005544605,0.0001296693,0.0001655743,0.000035516,0.0001646338,0.0002871819,0.00004745194],"category_scores_gemma":[0.0003030862,0.0002807544,0.0001152355,0.0005291153,0.0008910823,0.000120145,0.00009859844,0.0005739357,0.00001156515],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002122644,"about_ca_system_score_gemma":0.0006154318,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001703275,"about_ca_topic_score_gemma":0.00005227045,"domain_scores_codex":[0.9982353,0.00002431434,0.0004764313,0.0005322922,0.000361358,0.0003702352],"domain_scores_gemma":[0.9983053,0.0003194946,0.0001542684,0.0006954077,0.0002721796,0.0002533458],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001748243,0.0003028982,0.002093764,0.0005256278,0.0002098748,0.00003924877,0.0001187422,9.473425e-7,0.9658803,0.0004521402,0.02919466,0.001006983],"study_design_scores_gemma":[0.001586813,0.00008649637,0.00260709,0.0005263777,0.000324394,0.0002207192,0.0003155499,0.000008375391,0.9488131,0.0001991264,0.04507507,0.0002368958],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9670286,0.00160396,0.0002441121,0.006626028,0.0001705936,0.000332539,0.00009117689,0.0001630947,0.02373992],"genre_scores_gemma":[0.9962055,0.0009411332,0.0007901059,0.000339613,0.0003765595,0.00006352213,0.0002065652,0.00004233003,0.00103468],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02917691,"threshold_uncertainty_score":0.9999645,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01530307665233898,"score_gpt":0.2519484825486069,"score_spread":0.2366454058962679,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}