{"id":"W4408350434","doi":"10.1016/j.poly.2025.117494","title":"Europium(III) bis(terpyridine-trioxide) tetracyanoaurate(III) complexes supporting high nuclearity water clusters and exhibiting hydration-dependent quantum yields","year":2025,"lang":"en","type":"article","venue":"Polyhedron","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Terpyridine; Europium; Trioxide; Quantum chemical; Photochemistry; Inorganic chemistry; Molecule; Organic chemistry; Ion; Sulfur","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0007411025,0.0003280664,0.0004592764,0.0002091437,0.0006019392,0.0004618105,0.0002904847,0.0001211245,0.000707973],"category_scores_gemma":[0.00005518618,0.0002584223,0.000096608,0.0001777935,0.0001704268,0.0006270946,0.0002411877,0.0002506016,0.0001298715],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005304845,"about_ca_system_score_gemma":0.00005641088,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00245874,"about_ca_topic_score_gemma":0.0003387994,"domain_scores_codex":[0.9973422,0.0001984862,0.0007633189,0.0006509043,0.0003755005,0.0006695417],"domain_scores_gemma":[0.9990659,0.0001754443,0.0001662703,0.0003564773,0.00009704677,0.0001389104],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001082599,0.00007356662,0.0005934365,0.0001156474,0.00002273658,0.00003694171,0.0005607287,0.00005634385,0.9913532,0.00646421,0.0002602238,0.0003547271],"study_design_scores_gemma":[0.00152752,0.0001149956,0.00388856,0.0001309303,0.00008734286,0.00004248087,0.0005969353,0.001756596,0.9877947,0.002812134,0.0007926435,0.0004551697],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9907952,0.00009671974,0.00354743,0.001997246,0.0007913217,0.0003254155,0.00004029072,0.0002559125,0.002150496],"genre_scores_gemma":[0.9977195,0.00002978619,0.0004873224,0.0009037691,0.0001437943,0.00001526113,0.0000590738,0.00003196007,0.0006095536],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006924312,"threshold_uncertainty_score":0.9999868,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01329141589483885,"score_gpt":0.2554390057846734,"score_spread":0.2421475898898345,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}