{"id":"W4408403506","doi":"10.1002/ange.202502201","title":"Allenylidenphosphonium‐Ion: Ein Isoelektronisches Phosphor‐Analogon Von [3]Kumulen","year":2025,"lang":"de","type":"article","venue":"Angewandte Chemie","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Cumulene; Phosphonium; Phosphorus; Chemistry; Ion; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001686129,0.0002778722,0.0001491875,0.0001576816,0.000160452,0.0002313855,0.0002566284,0.0002638637,0.002243156],"category_scores_gemma":[0.0001361873,0.0001280018,0.0001321054,0.0001126946,0.0001815517,0.0001886821,0.0001787644,0.0003925599,0.0003494831],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001817772,"about_ca_system_score_gemma":0.0001711113,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003026864,"about_ca_topic_score_gemma":0.0004025599,"domain_scores_codex":[0.9998962,0.00002872574,0.000004679502,0.00002780124,0.00002280617,0.00001984676],"domain_scores_gemma":[0.9999272,0.00001868246,0.00001345949,0.00001209162,0.00001380836,0.00001470136],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000099214,0.00001473944,0.00004841446,0.00003467497,0.000004263669,0.00004112158,0.00002097557,0.00008875506,0.9986437,0.0001187888,0.00002154242,0.000863825],"study_design_scores_gemma":[0.00002050621,0.0003990808,0.0005420345,0.000003996742,0.0000080461,0.00009485592,0.0000167136,0.0002251326,0.996411,0.00006058206,0.002211067,0.000006789332],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9931732,0.0008736936,0.002760239,0.00006356398,0.00004682799,0.00002068201,0.00009134995,0.00007979631,0.002890592],"genre_scores_gemma":[0.9905555,0.0005694987,0.003620805,0.0001069358,0.00001443894,0.0000312386,0.0002212713,0.00002570068,0.004854643],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002243156,"threshold_uncertainty_score":0.007504106,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01076042241918928,"score_gpt":0.2343692097788163,"score_spread":0.223608787359627,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}