{"id":"W4408403506","doi":"10.1002/ange.202502201","title":"Allenylidenphosphonium‐Ion: Ein Isoelektronisches Phosphor‐Analogon Von [3]Kumulen","year":2025,"lang":"de","type":"article","venue":"Angewandte Chemie","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Cumulene; Phosphonium; Phosphorus; Chemistry; Ion; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","insufficient_payload"],"category_scores_codex":[0.0007208493,0.001767966,0.001882305,0.0003062484,0.0008331478,0.0006580879,0.002328515,0.001743852,0.009208342],"category_scores_gemma":[0.0006105587,0.001983466,0.001073991,0.001316737,0.0006719509,0.0004320131,0.001261255,0.001815042,0.003612355],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001483689,"about_ca_system_score_gemma":0.001134605,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008600384,"about_ca_topic_score_gemma":0.0001135172,"domain_scores_codex":[0.9923457,0.0001175063,0.00173676,0.00238128,0.001142813,0.00227594],"domain_scores_gemma":[0.9941525,0.0009206734,0.0006950606,0.003203339,0.0004160079,0.0006124337],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007839127,0.001174106,0.004834818,0.001885121,0.003826171,0.0003212515,0.001126958,0.00001576926,0.7312671,0.001263778,0.2469077,0.006593319],"study_design_scores_gemma":[0.001283662,0.00005391318,0.0001519448,0.0008321803,0.001073785,0.000009779854,0.0005543476,0.00002943715,0.606983,0.0008547355,0.3870774,0.00109582],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.3732916,0.3566977,0.0001613701,0.01256102,0.007380067,0.001116994,0.0006867225,0.001491064,0.2466135],"genre_scores_gemma":[0.8966097,0.01452872,0.000931542,0.001357003,0.00206419,0.0001967138,0.00041793,0.0003448659,0.08354938],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5233181,"threshold_uncertainty_score":0.9995521,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01076042241918928,"score_gpt":0.2343692097788163,"score_spread":0.223608787359627,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}