{"id":"W4409187672","doi":"10.1002/047084289x.rn02618","title":"5‐Chloro‐ <i>N</i> ‐(di‐ <i>tert</i> ‐butylphosphaneyl)‐ <i>N</i> ‐methylpyrazin‐2‐amine","year":2025,"lang":"en","type":"other","venue":"Encyclopedia of Reagents for Organic Synthesis","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Amine gas treating; Medicinal chemistry; Chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","insufficient_payload"],"category_scores_codex":[0.0004877652,0.001769919,0.002804799,0.0006836743,0.0001987758,0.00007508492,0.002579303,0.001831739,0.06227664],"category_scores_gemma":[0.002528008,0.001850228,0.001119921,0.0007963192,0.0003493186,0.0001260692,0.0006124322,0.0005957986,0.0008558747],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003527274,"about_ca_system_score_gemma":0.0008186183,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006464501,"about_ca_topic_score_gemma":0.0001951169,"domain_scores_codex":[0.9935976,0.00008436348,0.001792322,0.002015789,0.001108463,0.00140146],"domain_scores_gemma":[0.9919644,0.002597487,0.001721787,0.003054485,0.0002345772,0.0004272881],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0002029818,0.0007333169,0.0007227465,0.003500615,0.001827496,0.00003669903,0.00009804553,4.102779e-7,0.03710142,0.000124424,0.9084119,0.04723996],"study_design_scores_gemma":[0.0006511507,0.00003321625,0.00001229753,0.001335376,0.001185325,0.00000783031,0.00006740163,0.000004600661,0.3781615,0.0001052344,0.6174078,0.00102822],"study_design_candidate":"not_applicable","study_design_consensus":"not_applicable","genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.0006968544,0.008126219,0.0006611726,0.0002902299,0.002179579,0.001126916,0.004536089,0.001176326,0.9812066],"genre_scores_gemma":[0.003685218,0.01259524,0.004478469,0.0002044202,0.001318001,0.0006605305,0.000300464,0.002665363,0.9740923],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.3410601,"threshold_uncertainty_score":0.9999221,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006175547847002889,"score_gpt":0.2203457947522994,"score_spread":0.2141702469052965,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}