{"id":"W4409218813","doi":"10.1002/chem.202501148","title":"Photoredox‐Catalyzed Hydroalkylation of C(sp <sup>3</sup> )–H Acids","year":2025,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Alliance de recherche numérique du Canada; University of Ottawa","keywords":"Photoredox catalysis; Catalysis; Electron transfer; Chemistry; Catalytic cycle; Redox; Ligand (biochemistry); Lithium (medication); Radical; Combinatorial chemistry; Metal; Photochemistry; Organic chemistry; Photocatalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001333309,0.0002510723,0.0001391114,0.00006084727,0.0001053754,0.0002337573,0.0003182486,0.0002477449,0.002800589],"category_scores_gemma":[0.0001728583,0.00007289436,0.0001206707,0.00007576576,0.0001587497,0.0003197055,0.0002027338,0.0003449795,0.0005256181],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003073452,"about_ca_system_score_gemma":0.0001305127,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006541543,"about_ca_topic_score_gemma":0.001708364,"domain_scores_codex":[0.9999547,0.000003665367,0.000001477889,0.000008979855,0.00001414616,0.00001698236],"domain_scores_gemma":[0.9999665,0.00000968531,0.00001016308,0.000003780054,0.000005649327,0.000004276244],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003237028,0.00009795371,0.0006726866,0.0006336101,0.00005830804,0.0002269048,0.0001270846,0.004893998,0.9524182,0.007274729,0.002134584,0.0311382],"study_design_scores_gemma":[0.00003278269,0.000450595,0.0009239237,0.00001250243,0.00002115851,0.0001941067,0.00006953497,0.01012924,0.9760149,0.0006375776,0.01149917,0.00001445106],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9738643,0.001360634,0.01088049,0.000172398,0.00009869294,0.00006704649,0.0002580908,0.0002715129,0.01302688],"genre_scores_gemma":[0.9941944,0.0004521783,0.003235936,0.00004031884,0.00000843552,0.00001565464,0.0001415725,0.00002868478,0.001882809],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002800589,"threshold_uncertainty_score":0.009368896,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00903891680589222,"score_gpt":0.2338632101133239,"score_spread":0.2248242933074317,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}