{"id":"W4409360103","doi":"10.1139/cjc-2024-0233","title":"Polymeric N-heterocyclic carbenes in frustrated Lewis pair chemistry","year":2025,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"European Regional Development Fund; Engineering and Physical Sciences Research Council; Leverhulme Trust","keywords":"Chemistry; Frustrated Lewis pair; Lewis acids and bases; Computational chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001442652,0.0001809301,0.0001424228,0.0001004806,0.0002267027,0.0003124073,0.0002497961,0.0003068937,0.001636629],"category_scores_gemma":[0.0001003172,0.0001107725,0.00009888136,0.00008829459,0.0003951012,0.0004992951,0.0003425459,0.0003019244,0.0002838736],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003744337,"about_ca_system_score_gemma":0.000227914,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000565592,"about_ca_topic_score_gemma":0.001481828,"domain_scores_codex":[0.9999257,0.0000158418,0.000003004909,0.00001331522,0.00002077201,0.00002135614],"domain_scores_gemma":[0.9999671,0.00001031077,0.000005812955,0.000005359917,0.000003335356,0.000008078821],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001151571,0.0000930538,0.0002524325,0.0003162149,0.00001752377,0.0003826994,0.0001698286,0.005946388,0.9033987,0.07330748,0.0007600109,0.01524059],"study_design_scores_gemma":[0.0001524824,0.00115758,0.001298022,0.00003163784,0.00002672491,0.0006110079,0.00009044501,0.02730335,0.9082232,0.01563846,0.04540025,0.00006686568],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.941592,0.005508457,0.0180937,0.0002847592,0.00009163495,0.00007976856,0.0000766704,0.0001777659,0.0340953],"genre_scores_gemma":[0.9914021,0.001000191,0.003264298,0.00005374154,0.00001707723,0.00003057948,0.00003800578,0.000009542256,0.004184534],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001636629,"threshold_uncertainty_score":0.005475044,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005993540019688656,"score_gpt":0.2072137987567403,"score_spread":0.2012202587370516,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}