{"id":"W4409360172","doi":"10.1139/cjc-2024-0166","title":"Structural changes and CO<sub>2</sub> adsorption performance in Zn<sub>2</sub>(BDC)<sub>2</sub>DABCO metal-organic framework under high-pressure and high-temperature conditions","year":2025,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation","keywords":"Chemistry; High pressure; DABCO; Metal-organic framework; Adsorption; Metal; Inorganic chemistry; Physical chemistry; Octane; Thermodynamics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005106708,0.0002300303,0.0001292195,0.0001199453,0.0001282109,0.0001913552,0.0002164788,0.0002208779,0.0006316746],"category_scores_gemma":[0.0001686378,0.0001837667,0.0000902921,0.0001246938,0.0002201611,0.0002267288,0.0001567366,0.0002193222,0.00009291546],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002192122,"about_ca_system_score_gemma":0.000115137,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001638482,"about_ca_topic_score_gemma":0.002033778,"domain_scores_codex":[0.9999268,0.000004852076,0.00000350911,0.00001533983,0.00002806031,0.00002156465],"domain_scores_gemma":[0.9999403,0.000009985177,0.00002230228,0.000004880758,0.00001255154,0.00001001153],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006902741,0.000008053519,0.0003949129,0.00002340062,0.000003121409,0.00004957649,0.00001699728,0.0001772995,0.9986803,0.00003631261,0.00001990256,0.0005211117],"study_design_scores_gemma":[0.00000455224,0.00004827248,0.0066194,0.000001651491,0.000005877153,0.00007366531,0.00002492715,0.001819955,0.9911562,0.00001308964,0.0002277513,0.000004486017],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9993966,0.00008146139,0.0002479677,0.00001000083,0.000001941349,0.000001988104,0.00006297105,0.0000208068,0.0001763744],"genre_scores_gemma":[0.9993861,0.00006587099,0.000241635,0.000004852163,9.170853e-7,0.000003174878,0.00005596202,0.000004983337,0.0002365383],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001638482,"threshold_uncertainty_score":0.003257871,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006693218683209847,"score_gpt":0.2101004957450891,"score_spread":0.2034072770618793,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}