{"id":"W4409428265","doi":"10.1002/ange.202504498","title":"Eine spannende Reise: Wolfram(VI)‐ und Wolfram(V)‐Fluoride treffen auf <i>N</i> ‐Heterocyclische Carbene und cyclische (Alkyl)(Amino)carbene","year":2025,"lang":"de","type":"article","venue":"Angewandte Chemie","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Julius-Maximilians-Universität Würzburg","keywords":"Tungsten; Carbene; Alkyl; Chemistry; Medicinal chemistry; Polymer chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002053855,0.0004956028,0.0002467621,0.0002153499,0.0003293191,0.0003057897,0.0004926104,0.0004909559,0.005774826],"category_scores_gemma":[0.0002202886,0.0001916408,0.0003934259,0.0001208423,0.0002790986,0.0004778671,0.0003328482,0.0005792105,0.00101442],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002422139,"about_ca_system_score_gemma":0.0002603172,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001766888,"about_ca_topic_score_gemma":0.001148131,"domain_scores_codex":[0.9998758,0.00001120087,0.0000057733,0.00003006489,0.00004180004,0.00003541128],"domain_scores_gemma":[0.9999139,0.00001828489,0.00001436512,0.00001699261,0.00002403457,0.00001223886],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001949597,0.00003658202,0.0001630762,0.0001375373,0.00001669494,0.0002035074,0.000151506,0.0004780628,0.9863585,0.001098407,0.0004088211,0.0107524],"study_design_scores_gemma":[0.00003610181,0.001013548,0.0008754767,0.00001383944,0.00001736627,0.0003966815,0.00005797313,0.0007553379,0.9800903,0.0004197073,0.01630171,0.00002187895],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9595184,0.005050869,0.01233029,0.0002945973,0.0002463162,0.0001459349,0.0003485705,0.0005101913,0.02155488],"genre_scores_gemma":[0.9589169,0.002887546,0.007990835,0.0002408111,0.00005325309,0.00009975949,0.0006449486,0.0001101876,0.02905576],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005774826,"threshold_uncertainty_score":0.0193187,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01479566106268871,"score_gpt":0.2645653188708144,"score_spread":0.2497696578081257,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}