{"id":"W4409428266","doi":"10.1002/anie.202504498","title":"A Joyful Journey: Tungsten(VI) and Tungsten(V) Fluorides Meet <i>N</i> ‐Heterocyclic Carbenes and Cyclic (Alkyl)(Amino)Carbenes","year":2025,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Julius-Maximilians-Universität Würzburg","keywords":"Carbene; IMes; Chemistry; Tungsten; Fluoride; Medicinal chemistry; Alkyl; Trigonal bipyramidal molecular geometry; Electron paramagnetic resonance; Crystallography; Polymer chemistry; Stereochemistry; Inorganic chemistry; Crystal structure; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001554959,0.0005587938,0.0005321106,0.0003408925,0.00211038,0.003181252,0.000811124,0.002259335,0.01359759],"category_scores_gemma":[0.002257331,0.0002811224,0.0004411383,0.0002331481,0.001984686,0.006675135,0.002698553,0.004248664,0.003759005],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001292676,"about_ca_system_score_gemma":0.001065561,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001074652,"about_ca_topic_score_gemma":0.001965487,"domain_scores_codex":[0.9990252,0.0003005445,0.00002311395,0.00008173892,0.0003600219,0.0002093596],"domain_scores_gemma":[0.9991829,0.0002093607,0.00004012831,0.00006412932,0.0001637859,0.0003396817],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008393838,0.000311281,0.0008627931,0.0009202468,0.00008187233,0.001257667,0.007598762,0.0005532367,0.03876554,0.2040146,0.4998374,0.2449572],"study_design_scores_gemma":[0.00005466357,0.0002904175,0.0002926833,0.0002109559,0.00001107513,0.0006524345,0.003493426,0.0003140585,0.006702786,0.02774714,0.9601767,0.00005376946],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"commentary","genre_gemma":"empirical","genre_scores_codex":[0.1003857,0.3025548,0.0188139,0.340469,0.06355295,0.0002254617,0.0005065718,0.001962574,0.171529],"genre_scores_gemma":[0.5248852,0.09947702,0.02205865,0.07648667,0.01879696,0.0002081907,0.0005027298,0.0007818404,0.2568029],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.01359759,"threshold_uncertainty_score":0.04548842,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00823683386715836,"score_gpt":0.2357376614619551,"score_spread":0.2275008275947967,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}