{"id":"W4409428266","doi":"10.1002/anie.202504498","title":"A Joyful Journey: Tungsten(VI) and Tungsten(V) Fluorides Meet <i>N</i> ‐Heterocyclic Carbenes and Cyclic (Alkyl)(Amino)Carbenes","year":2025,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Julius-Maximilians-Universität Würzburg","keywords":"Carbene; IMes; Chemistry; Tungsten; Fluoride; Medicinal chemistry; Alkyl; Trigonal bipyramidal molecular geometry; Electron paramagnetic resonance; Crystallography; Polymer chemistry; Stereochemistry; Inorganic chemistry; Crystal structure; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001434025,0.000389423,0.0003659451,0.0002135079,0.0002670113,0.000279608,0.0003266534,0.0003645433,0.0002893271],"category_scores_gemma":[0.0001257528,0.0003681446,0.0001395274,0.000175883,0.0001979341,0.000439896,0.0002478637,0.0003780483,0.000009301916],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001973609,"about_ca_system_score_gemma":0.00005342673,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001704975,"about_ca_topic_score_gemma":0.00004625207,"domain_scores_codex":[0.9980283,0.00001667389,0.0005371473,0.0006162131,0.0004263936,0.0003752469],"domain_scores_gemma":[0.9988973,0.0002011935,0.0002126041,0.000288875,0.0002481538,0.0001518579],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001238794,0.0001149185,0.004476765,0.0002568745,0.0005428817,0.00004769698,0.0003446907,0.000008866567,0.9751746,0.002078658,0.01387941,0.002950762],"study_design_scores_gemma":[0.001420597,0.00003007513,0.001029025,0.000492457,0.0001781282,0.0002116614,0.000419445,0.0003268547,0.9591628,0.004173821,0.03215168,0.0004034781],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9342437,0.004724739,0.0001817285,0.0032765,0.002469178,0.0001347548,0.0001470802,0.0002243157,0.05459799],"genre_scores_gemma":[0.9910671,0.002363946,0.0001355222,0.0005608686,0.001617874,0.00005062442,0.0002880312,0.00004085351,0.003875198],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05682337,"threshold_uncertainty_score":0.999877,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00823683386715836,"score_gpt":0.2357376614619551,"score_spread":0.2275008275947967,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}