{"id":"W4409637912","doi":"10.20944/preprints202504.1546.v1","title":"Heat-Induced Mn2+ and Fe2+ Oxidation in Heterophyllosilicates with Porous Structure: Kupletskite and Kupletskite-(Cs)","year":2025,"lang":"en","type":"preprint","venue":"Preprints.org","topic":"Zeolite Catalysis and Synthesis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Russian Science Foundation; Saint Petersburg State University","keywords":"Porosity; Materials science; Chemistry; Crystallography; Chemical engineering; Composite material; Engineering","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005108948,0.0001671708,0.0001312757,0.0001428042,0.0001032077,0.000190557,0.0002015033,0.0001555304,0.0005372434],"category_scores_gemma":[0.0001478702,0.0001462898,0.0001209302,0.0001113776,0.0002319304,0.0001579861,0.0001889866,0.0001800716,0.0000746576],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000222518,"about_ca_system_score_gemma":0.0001234386,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001141708,"about_ca_topic_score_gemma":0.002193898,"domain_scores_codex":[0.9999433,0.000004138444,0.000004116271,0.0000156817,0.00001643459,0.00001627382],"domain_scores_gemma":[0.999936,0.000008475195,0.0000238291,0.000005749905,0.00001170124,0.00001428028],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001011914,0.000006114473,0.0009042607,0.00003314702,0.000007255482,0.00005145661,0.00002978052,0.0001403656,0.9981102,0.00004434484,0.00001682086,0.0005550598],"study_design_scores_gemma":[0.00001640456,0.0001397267,0.01791748,0.000003604119,0.00001082045,0.0001955232,0.00007352847,0.00118965,0.9797755,0.00003061681,0.0006407069,0.000006500122],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9996502,0.00005765487,0.00008366899,0.000003394947,0.000001254049,0.000002185338,0.00004638389,0.000006537855,0.0001486559],"genre_scores_gemma":[0.9994013,0.00003040972,0.0001944282,0.000002842577,8.031945e-7,0.000004305179,0.00009412037,0.000004060139,0.000267672],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001141708,"threshold_uncertainty_score":0.002270162,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0469110840582742,"score_gpt":0.2919006746043457,"score_spread":0.2449895905460715,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}