{"id":"W4409662345","doi":"10.1016/j.jqsrt.2025.109469","title":"Measurements of infrared absorption cross-sections for 1H-perfluorohexane and perfluoro-2-methyl-2-pentene from 300 to 340 K","year":2025,"lang":"en","type":"article","venue":"Journal of Quantitative Spectroscopy and Radiative Transfer","topic":"Per- and polyfluoroalkyl substances research","field":"Environmental Science","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo; University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Pentene; Infrared; Absorption (acoustics); Materials science; Chemistry; Physics; Organic chemistry; Optics; Composite material; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000656576,0.0001934432,0.000426091,0.0002059475,0.0002273698,0.00005868443,0.0001745374,0.00008005913,0.0003197481],"category_scores_gemma":[0.0001479081,0.000158629,0.0001233597,0.0003693944,0.0004009434,0.000448855,0.00002721651,0.0002405649,0.000005376696],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001662309,"about_ca_system_score_gemma":0.00005811686,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002207174,"about_ca_topic_score_gemma":0.0002748988,"domain_scores_codex":[0.9983433,0.0001644843,0.0005254423,0.0002810374,0.0004004762,0.0002852016],"domain_scores_gemma":[0.999107,0.0003449346,0.0000878338,0.0001062503,0.0001772703,0.0001767044],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002151194,0.0002015849,0.1097625,0.00004600096,0.0002828384,0.000002553994,0.004397837,0.0009567671,0.87782,0.0005427236,0.0005875822,0.003248325],"study_design_scores_gemma":[0.00247747,0.001785705,0.4771364,0.0001155358,0.00009461098,0.000003313979,0.0007207089,0.0004611577,0.512856,0.002589713,0.001565202,0.000194217],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9432203,0.006030688,0.04835575,0.0004402761,0.0001710243,0.000426505,0.0001540159,0.000005394161,0.001196058],"genre_scores_gemma":[0.9825562,0.001240875,0.01561411,0.0001693742,0.00004404712,0.00002078241,0.000005991755,0.00001319756,0.0003354804],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3673738,"threshold_uncertainty_score":0.6468705,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0425981846167366,"score_gpt":0.3664655610972676,"score_spread":0.323867376480531,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}