{"id":"W4409876097","doi":"10.5539/ijc.v17n2p10","title":"Buswell’s Model for Calculating Theoretical Higher Heating Value of Organic Matter","year":2025,"lang":"en","type":"article","venue":"International Journal of Chemistry","topic":"thermodynamics and calorimetric analyses","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Value (mathematics); Organic matter; Thermodynamics; Environmental chemistry; Organic chemistry; Statistics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001616088,0.0001097238,0.0002241846,0.00005489428,0.00002531356,0.00002943963,0.0004406714,0.0001045649,0.001607718],"category_scores_gemma":[0.0001728039,0.00009716986,0.0002404128,0.00007874406,0.00007475385,0.00005054012,0.0000711823,0.0001858894,0.000001052109],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000123381,"about_ca_system_score_gemma":0.0001279127,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003254732,"about_ca_topic_score_gemma":8.643723e-8,"domain_scores_codex":[0.99887,0.00000487579,0.0005693274,0.0001144377,0.0003229698,0.000118387],"domain_scores_gemma":[0.9987372,0.0001980431,0.0003716429,0.0001148696,0.000534023,0.0000442796],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001707636,0.0001312284,0.004187187,0.0001791851,0.0006737578,0.000007665877,0.00006306217,0.006250879,0.9726206,0.01426455,0.0004165861,0.001034525],"study_design_scores_gemma":[0.001356535,0.000008558684,0.0001903172,0.0004619022,0.0002004776,0.00004164368,0.0001219359,0.2927398,0.6632365,0.04122735,0.0002287636,0.0001862167],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8807945,0.0002156139,0.09163291,0.0006527948,0.0001964905,0.00001868561,0.00003026084,0.000007973554,0.0264508],"genre_scores_gemma":[0.9949292,0.000009944248,0.00202582,0.0001297317,0.0002698856,0.000001550048,0.000009168405,0.00001466087,0.002610074],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3093841,"threshold_uncertainty_score":0.999305,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007779095736323952,"score_gpt":0.2801719650476416,"score_spread":0.2723928693113176,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}