{"id":"W4409910633","doi":"10.1002/ange.202507571","title":"Xanthopinacol Boronate: A Robust, Photochemically Assembled and Cleavable Boronic Ester for Orthogonal Chemistry","year":2025,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Boronic acid; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002209722,0.000588551,0.0001372818,0.0002054217,0.0001201894,0.0002200429,0.000241605,0.0004064113,0.001194781],"category_scores_gemma":[0.0001336486,0.0001873337,0.0001558899,0.0001880987,0.0001806243,0.0004374349,0.0003573965,0.0003971126,0.0006216004],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002517584,"about_ca_system_score_gemma":0.0001626503,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002312252,"about_ca_topic_score_gemma":0.0003814046,"domain_scores_codex":[0.9998847,0.0000203023,0.000009793707,0.00003154213,0.00002832639,0.0000252869],"domain_scores_gemma":[0.9999192,0.000007486472,0.00003075912,0.000009701122,0.00001129539,0.00002157179],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004923157,0.00001439402,0.00004969674,0.00009074696,0.000007024519,0.00005973085,0.00001371053,0.000119375,0.9958663,0.0005047733,0.0001430952,0.003081978],"study_design_scores_gemma":[0.00001239224,0.00009990093,0.0002030461,0.000004524028,0.000005674803,0.00007284247,0.000004636855,0.0005650217,0.9950141,0.00003930891,0.003972053,0.000006529143],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9227138,0.006849585,0.05646572,0.0003545278,0.0002004481,0.0001926711,0.0007969274,0.0005241754,0.0119022],"genre_scores_gemma":[0.9695222,0.002267498,0.02256803,0.0001074521,0.00002837071,0.00009973051,0.0003728684,0.00007159205,0.00496226],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001194781,"threshold_uncertainty_score":0.003996909,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0112323447605905,"score_gpt":0.2483297540517104,"score_spread":0.2370974092911199,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}