{"id":"W4409995239","doi":"10.1002/ange.202506476","title":"Hochgradig enantioselektive Organokatalyse mit zweizähnigen Halogenbrückendonoren","year":2025,"lang":"de","type":"article","venue":"Angewandte Chemie","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Centre in Green Chemistry and Catalysis; Université de Sherbrooke","funders":"","keywords":"Enantioselective synthesis; Organocatalysis; Chemistry; Denticity; Halogen; Halogen bond; Combinatorial chemistry; Stereochemistry; Organic chemistry; Catalysis; Crystal structure","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0004262929,0.0009424173,0.001285121,0.0004869987,0.0004676713,0.0002714598,0.001281302,0.0008503507,0.002697997],"category_scores_gemma":[0.0007636606,0.000929544,0.0009544825,0.002507848,0.0003748877,0.0002224602,0.000544182,0.0006564406,0.001889819],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005762887,"about_ca_system_score_gemma":0.0005461998,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003651798,"about_ca_topic_score_gemma":0.00003475213,"domain_scores_codex":[0.9955305,0.00006616131,0.001048851,0.001493023,0.000636948,0.001224537],"domain_scores_gemma":[0.9963703,0.0005975686,0.0004719768,0.001829816,0.0003493962,0.0003809286],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003660031,0.001670755,0.02392941,0.001678924,0.01726607,0.0004230857,0.002100785,0.000005077988,0.5347905,0.0007392576,0.3231855,0.09384465],"study_design_scores_gemma":[0.0009433784,0.00001840022,0.0004057061,0.0002626484,0.002850582,0.000006243819,0.0007039633,0.000007955453,0.7779173,0.0002930196,0.2158681,0.0007226646],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.1176518,0.2491794,0.0006874238,0.003108342,0.002510416,0.0008044769,0.001737882,0.0006982287,0.6236221],"genre_scores_gemma":[0.9321479,0.006064797,0.0002600613,0.0006346867,0.001486466,0.0001133072,0.00127946,0.000133489,0.05787981],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.8144962,"threshold_uncertainty_score":0.9993155,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01079183506974176,"score_gpt":0.2369055289401574,"score_spread":0.2261136938704156,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}