{"id":"W4410023577","doi":"10.1139/cjc-2024-0253","title":"Synthesis and characterisation of <i>tris</i> (2,4-xylyl)phosphane oxide and the heavier chalcogen derivatives of <i>tris</i> (2,4-xylyl)- and <i>tris</i> (3,5-xylyl)phosphane","year":2025,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Toronto Metropolitan University","funders":"","keywords":"Tris; Chemistry; Chalcogen; Oxide; Stereochemistry; Medicinal chemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001192371,0.000157481,0.00009452389,0.0001649091,0.0001184497,0.0001932941,0.0001551474,0.0001614202,0.0008911458],"category_scores_gemma":[0.0001587594,0.0001104379,0.00008322037,0.0001682044,0.0001521608,0.0001554364,0.0001572496,0.0001779777,0.0003398251],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001202337,"about_ca_system_score_gemma":0.0002096197,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004073395,"about_ca_topic_score_gemma":0.0008462754,"domain_scores_codex":[0.9999316,0.000005750932,0.000005595971,0.00001514649,0.00003262157,0.000009233678],"domain_scores_gemma":[0.9998952,0.00001409771,0.00002765374,0.00001168848,0.00003135944,0.00002000709],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001370951,0.000003444572,0.0001389766,0.00001768352,9.458121e-7,0.00004044569,0.00002279014,0.00004060875,0.9987607,0.00004589776,0.00001485956,0.000900015],"study_design_scores_gemma":[0.000002245119,0.0001046189,0.00149347,0.000001974682,0.000002782067,0.0001057397,0.00002255356,0.0001698784,0.9959874,0.00001724168,0.00208981,0.00000229772],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9936603,0.0002274367,0.003924803,0.00002420425,0.000005961011,0.00003583322,0.0003200405,0.00005036018,0.001751135],"genre_scores_gemma":[0.9843541,0.0004478498,0.009730213,0.00002059877,0.000005356386,0.00004539163,0.001063183,0.00006307007,0.004270207],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008911458,"threshold_uncertainty_score":0.002981186,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01070025988490187,"score_gpt":0.212807810200027,"score_spread":0.2021075503151251,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}