{"id":"W4410138308","doi":"10.1021/acscatal.4c07724","title":"Insights into C–N Bond Formation through the Coreduction of Nitrite and CO<sub>2</sub>: Guiding Selectivity Toward C–N Bond","year":2025,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Ammonia Synthesis and Nitrogen Reduction","field":"Chemical Engineering","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Bond; Catalysis; Selectivity; Nitrite; Chemistry; Business; Organic chemistry; Nitrate","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001434028,0.0001596216,0.000265505,0.0001346923,0.0001986893,0.00003451735,0.0001184798,0.0001166604,0.000001902323],"category_scores_gemma":[0.0001638349,0.0001272167,0.00009816595,0.000682551,0.00009237786,0.0004972725,0.000063802,0.0001257819,0.000005128104],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001160591,"about_ca_system_score_gemma":0.0000261193,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002412973,"about_ca_topic_score_gemma":0.00003404902,"domain_scores_codex":[0.999053,0.00003083559,0.0003405602,0.0002348995,0.0001867448,0.0001539799],"domain_scores_gemma":[0.9993135,0.0001245225,0.000152713,0.0002640184,0.0001150301,0.00003021769],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002525123,0.00003604304,0.00008744505,0.0001015097,0.000158224,3.341781e-7,0.001934742,0.0001072091,0.9810672,0.001465339,0.0007299709,0.0142867],"study_design_scores_gemma":[0.0001554522,0.00001276117,0.0002984529,0.00004281567,0.0002239603,0.000006021548,0.0009840927,0.00177824,0.9937805,0.001916456,0.0006789415,0.0001222919],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.985191,0.001412802,0.01214801,0.0004631401,0.00008848553,0.0001505828,0.00000357286,0.00005860994,0.000483821],"genre_scores_gemma":[0.9991126,0.0002882185,0.0003763154,0.0000299062,0.00007044477,0.00003134161,0.0000520197,0.00001394456,0.00002519549],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01416441,"threshold_uncertainty_score":0.5187746,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01539623200661713,"score_gpt":0.238628785589896,"score_spread":0.2232325535832788,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}