{"id":"W4410206038","doi":"10.1002/ange.202505179","title":"Nucleophilic Covalent Ligands Enable Simultaneous Surface Reconstruction and Passivation of Colloidal InSb Quantum Dots for Stable Short‐Wave Infrared Photodetectors","year":2025,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Quantum Dots Synthesis And Properties","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo; University of Toronto","funders":"Mitacs","keywords":"Passivation; Photodetector; Infrared; Covalent bond; Quantum dot; Colloid; Nucleophile; Materials science; Optoelectronics; Photochemistry; Chemistry; Nanotechnology; Optics; Physical chemistry; Physics; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008872867,0.0003338518,0.0001223397,0.00009676671,0.0001102487,0.0002110697,0.0001922775,0.0002043623,0.0006862718],"category_scores_gemma":[0.0001000042,0.0001418588,0.0001223093,0.00007549136,0.0001807813,0.0001527656,0.0002112896,0.0002384105,0.0001931163],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002733427,"about_ca_system_score_gemma":0.0001331419,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007013876,"about_ca_topic_score_gemma":0.001629772,"domain_scores_codex":[0.9999244,0.000007039046,0.000005667285,0.00002157665,0.00002515688,0.00001608975],"domain_scores_gemma":[0.9999516,0.000008137882,0.00001524609,0.000006511994,0.00001088796,0.0000076816],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000006896716,0.000004332275,0.00003797153,0.0000102248,0.000001478619,0.000007354648,0.000006519306,0.00004123422,0.9992917,0.00005078352,0.00001725649,0.0005243588],"study_design_scores_gemma":[0.000002128354,0.00002548929,0.00016164,6.538867e-7,0.000001798491,0.00001147133,0.000003825204,0.0005368969,0.9989478,0.000004955991,0.0003019709,0.000001407102],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9885576,0.000573557,0.009265671,0.00005186623,0.00001837062,0.00003107556,0.0001427544,0.0001340947,0.001224965],"genre_scores_gemma":[0.9918751,0.0002660797,0.006373142,0.00002769495,0.000003005429,0.00002409622,0.00009280741,0.00002272338,0.001315318],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007013876,"threshold_uncertainty_score":0.002295732,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02091613534661269,"score_gpt":0.2364271412871106,"score_spread":0.2155110059404979,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}