{"id":"W4410239723","doi":"10.26434/chemrxiv-2025-gqc99","title":"N-Heterocyclic Carbenes as Clickable Molecular Anchors for Electrochemical Surface Functionalization","year":2025,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University; Queen's University; McGill University","funders":"Queen's University","keywords":"Surface modification; Electrochemistry; Combinatorial chemistry; Chemistry; Nanotechnology; Computer science; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002077953,0.0003423714,0.0001811426,0.0002073498,0.00009414221,0.0003059309,0.0004028603,0.0003493194,0.001017685],"category_scores_gemma":[0.0002557613,0.0001317922,0.0001323146,0.0001807244,0.0002010638,0.0002894971,0.0002290688,0.0003373752,0.0002671737],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003665139,"about_ca_system_score_gemma":0.0001382163,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008202533,"about_ca_topic_score_gemma":0.00175194,"domain_scores_codex":[0.9997916,0.00002573325,0.00001045761,0.00005367567,0.00008463839,0.00003391202],"domain_scores_gemma":[0.9998932,0.00003822751,0.00002257935,0.00001376648,0.00001706639,0.00001526758],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000348351,0.00001331946,0.00005606025,0.00004937241,0.000004258984,0.00003958262,0.00001189775,0.0001683721,0.9955961,0.0003752811,0.00008745567,0.003563416],"study_design_scores_gemma":[0.000004245237,0.00004755235,0.000305549,0.000002049077,0.000003573065,0.00004443765,0.00000517736,0.000788384,0.996909,0.00003711332,0.001848671,0.000004221803],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.959938,0.005126386,0.02437597,0.0002159049,0.0001425508,0.0001085308,0.0004283634,0.0003805875,0.009283704],"genre_scores_gemma":[0.9866123,0.001415145,0.008395306,0.00006740011,0.00002088342,0.00004208088,0.0001973988,0.00002204274,0.003227478],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001017685,"threshold_uncertainty_score":0.003404498,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009429128198213853,"score_gpt":0.257649671542429,"score_spread":0.2482205433442151,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}