{"id":"W4410289538","doi":"10.1021/acsomega.4c10337","title":"Optimal Wavelengths and Solvents to Modulate Diazirine Kinetics","year":2025,"lang":"en","type":"article","venue":"ACS Omega","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Ministry of Education - Singapore; National Research Foundation Singapore; Singapore's National Water Agency; Agency for Science, Technology and Research","keywords":"Diazirine; Kinetics; Wavelength; Chemistry; Physics; Photochemistry; Optics; Classical mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00002543614,0.00009845658,0.0001117241,0.00003658818,0.00003841647,0.00002612764,0.00009557665,0.00007522207,0.00004498346],"category_scores_gemma":[0.00008212258,0.00009619909,0.00002792498,0.0001069986,0.00001531725,0.00002974657,0.0001484534,0.0001053637,0.00002046608],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003759289,"about_ca_system_score_gemma":0.00001141684,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001369304,"about_ca_topic_score_gemma":0.000002461088,"domain_scores_codex":[0.9994118,0.000001611358,0.0001211557,0.0001990783,0.00008357998,0.0001828345],"domain_scores_gemma":[0.9995918,0.00004068884,0.00001826261,0.0002156994,0.00003132162,0.0001022588],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001454246,0.00006085889,0.00005834234,0.00003507028,0.00002106828,0.000003714636,0.00002823205,0.00002156913,0.9762944,0.0008636186,0.0008666856,0.02173189],"study_design_scores_gemma":[0.0003408113,0.0000141525,0.000161283,0.00004208851,0.00002081239,0.000003567959,0.00003472435,0.0003478003,0.9175028,0.0007191267,0.08070067,0.0001121643],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.983245,0.00006565699,0.0006662562,0.0004233304,0.00008356474,0.00003986598,0.00001227226,0.00004914046,0.01541497],"genre_scores_gemma":[0.9865448,0.00005800918,0.00198268,0.0001977511,0.00005297193,0.0000142957,0.00001186845,0.00001079939,0.01112675],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07983399,"threshold_uncertainty_score":0.3922885,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008394298948492033,"score_gpt":0.252276330124015,"score_spread":0.2438820311755229,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}