{"id":"W4410289538","doi":"10.1021/acsomega.4c10337","title":"Optimal Wavelengths and Solvents to Modulate Diazirine Kinetics","year":2025,"lang":"en","type":"article","venue":"ACS Omega","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Ministry of Education - Singapore; National Research Foundation Singapore; Singapore's National Water Agency; Agency for Science, Technology and Research","keywords":"Diazirine; Kinetics; Wavelength; Chemistry; Physics; Photochemistry; Optics; Classical mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003932097,0.0005130835,0.0002193067,0.0002978877,0.0001991254,0.0004930978,0.0002951025,0.0002775444,0.0012107],"category_scores_gemma":[0.0007660402,0.0001759444,0.0001418466,0.0003114951,0.0002942269,0.0005676327,0.0003163778,0.0005724841,0.0005338541],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003201887,"about_ca_system_score_gemma":0.0002570861,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003652204,"about_ca_topic_score_gemma":0.0009690566,"domain_scores_codex":[0.9997414,0.00002788604,0.00002153827,0.00009124223,0.00006814288,0.00004971111],"domain_scores_gemma":[0.9996653,0.0001551442,0.00007204225,0.00002717601,0.00006127649,0.0000190954],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006306121,0.00001941997,0.0002331562,0.00006664333,0.000002952567,0.00002032001,0.00003833653,0.0002431299,0.9970482,0.0001393044,0.00006059548,0.002064856],"study_design_scores_gemma":[0.00000184195,0.00003643798,0.0003097843,0.000004235868,0.00000279572,0.0000136095,0.00001347722,0.0003693369,0.9987432,0.00002722042,0.0004743432,0.000003841121],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9771751,0.00210872,0.01562392,0.0001214072,0.00004383135,0.0000650945,0.0005348765,0.0003030039,0.004024107],"genre_scores_gemma":[0.9800588,0.002388806,0.01514994,0.00006251295,0.00001068347,0.0001431912,0.0002676299,0.0001419868,0.001776526],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0012107,"threshold_uncertainty_score":0.004050136,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008394298948492033,"score_gpt":0.252276330124015,"score_spread":0.2438820311755229,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}