{"id":"W4410313900","doi":"10.1021/jacs.5c03524","title":"4,4′-Hydrazobis(1-methylpyridinium) as a Two-Electron Posolyte Molecule for Aqueous Organic Redox Flow Batteries","year":2025,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Advanced battery technologies research","field":"Engineering","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"Concordia University; Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Fonds de recherche du Québec – Nature et technologies; Natural Sciences and Engineering Research Council of Canada; Courtois Foundation; Université de Montréal; Concordia University","keywords":"Chemistry; Redox; Aqueous solution; Molecule; Organic molecules; Electron; Photochemistry; Flow (mathematics); Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001995593,0.0002146088,0.0004408781,0.00004954546,0.0001023749,0.00004411138,0.0009303784,0.00008730172,0.00001591717],"category_scores_gemma":[0.0004145516,0.000159974,0.0005080277,0.000753627,0.0004099125,0.0001018741,0.0002447766,0.0008649286,0.000004020564],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005303728,"about_ca_system_score_gemma":0.0001176768,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005347067,"about_ca_topic_score_gemma":6.896259e-7,"domain_scores_codex":[0.9985936,0.00002779605,0.0003970552,0.0001761264,0.0002979508,0.0005074465],"domain_scores_gemma":[0.9989126,0.0002780705,0.0002051904,0.0003855194,0.000148456,0.00007015917],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006658841,0.00002637329,0.00005205221,0.00004134886,0.0001965331,0.000002723308,0.0000726537,0.001019982,0.9712447,0.0000152446,0.01898354,0.008278286],"study_design_scores_gemma":[0.0004917657,0.000133172,0.00002814215,0.00004346596,0.00004934902,0.00005283154,0.0002028053,0.003671374,0.9856494,0.003196966,0.006312547,0.0001681458],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.968619,0.0004900796,0.02466185,0.005418938,0.0002011478,0.0001999775,0.000009457887,0.0001463837,0.0002531834],"genre_scores_gemma":[0.9855221,0.0002879769,0.01267288,0.001122122,0.000139634,0.0000199876,0.000001439391,0.00004984419,0.0001840363],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0169031,"threshold_uncertainty_score":0.6523552,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005410565173724857,"score_gpt":0.2721018796645877,"score_spread":0.2666913144908628,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}