{"id":"W4410505047","doi":"10.26434/chemrxiv-2025-rtvqx","title":"Reduced Flow Battery Capacity Fade from Mixed Redox-Active Organics Beyond the Rule of Mixtures","year":2025,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; Office of Science; U.S. Department of Energy","keywords":"Redox; Fade; Flow (mathematics); Battery (electricity); Flow battery; Environmental science; Chemistry; Computer science; Inorganic chemistry; Thermodynamics; Mechanics; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002236997,0.0003726972,0.0002750857,0.0001667235,0.0001442281,0.0005565157,0.0004096725,0.0004245152,0.001434084],"category_scores_gemma":[0.000326864,0.0001903501,0.0002354919,0.0001272069,0.0002565137,0.0009386395,0.0004212345,0.000715057,0.0006743589],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002444627,"about_ca_system_score_gemma":0.0001345697,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002585023,"about_ca_topic_score_gemma":0.0005832982,"domain_scores_codex":[0.9998184,0.00001733015,0.00001015214,0.00004458706,0.00007556436,0.00003397871],"domain_scores_gemma":[0.9998999,0.00002339217,0.00001998091,0.00001369816,0.00003082545,0.00001210768],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007367644,0.00002268145,0.0001331374,0.0001029158,0.00001329044,0.0001076467,0.00003554279,0.0002440316,0.9907493,0.000750803,0.0002644983,0.007502348],"study_design_scores_gemma":[0.00000473306,0.00008358267,0.000161536,0.000007020323,0.000007802842,0.00007939521,0.00001582557,0.0009940685,0.9932934,0.0001697934,0.005178086,0.000004764266],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9404213,0.005767521,0.04350216,0.0006773344,0.0002936839,0.00005846886,0.0004959357,0.0007692876,0.008014357],"genre_scores_gemma":[0.9826806,0.001907072,0.0084684,0.000225318,0.00003156034,0.00004363039,0.0003139926,0.00007334977,0.006256056],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001434084,"threshold_uncertainty_score":0.004797518,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01223304930484251,"score_gpt":0.2314061284852702,"score_spread":0.2191730791804277,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}