{"id":"W4410613368","doi":"10.1039/d5fd00050e","title":"Borane-catalysed cyclodepolymerization of CO <sub>2</sub> -derived polycarbonates","year":2025,"lang":"en","type":"article","venue":"Faraday Discussions","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Department of Industry, Energy and Technology; Natural Sciences and Engineering Research Council of Canada; Memorial University of Newfoundland; Canada Foundation for Innovation","keywords":"Borane; Chemistry; Materials science; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001227448,0.0004394825,0.0001705287,0.0001391286,0.000225583,0.0002153275,0.0001922044,0.0003540887,0.002444256],"category_scores_gemma":[0.000268657,0.0001556338,0.0001629717,0.0001409538,0.000234922,0.000240948,0.0001485808,0.000425395,0.0005035868],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002227421,"about_ca_system_score_gemma":0.0002727177,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007131745,"about_ca_topic_score_gemma":0.002288349,"domain_scores_codex":[0.9998369,0.0000132427,0.000008367451,0.00003944147,0.00003594435,0.00006604258],"domain_scores_gemma":[0.9997876,0.00008047428,0.00005343724,0.00002007332,0.00002870677,0.00002975802],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000539469,0.00001160046,0.00005072305,0.00004883537,0.000003146079,0.00005056334,0.000008957089,0.00005540621,0.9983503,0.0001033153,0.00003957076,0.001223741],"study_design_scores_gemma":[0.000001577519,0.00004397291,0.0003668056,0.000002092661,0.000001570098,0.00003705692,0.000004263564,0.00005294179,0.9984618,0.00000708454,0.001019159,0.000001658405],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9750037,0.003228205,0.00674816,0.0001875998,0.0001623482,0.00009976292,0.0003136344,0.000113092,0.01414356],"genre_scores_gemma":[0.9901078,0.001290495,0.003642458,0.0001039381,0.0000211047,0.00004210996,0.0002243117,0.00004892225,0.00451887],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002444256,"threshold_uncertainty_score":0.008176863,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007239964053875662,"score_gpt":0.2476478646344904,"score_spread":0.2404079005806147,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}