{"id":"W4410872203","doi":"10.1002/anie.202508835","title":"Chemical Bond Covalency in Superionic Halide Solid‐State Electrolytes","year":2025,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Advanced Battery Materials and Technologies","field":"Engineering","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Oak Ridge National Laboratory; Natural Sciences and Engineering Research Council of Canada; National Key Research and Development Program of China; Canadian Institutes of Health Research; Natural Science Foundation of Beijing Municipality; National Natural Science Foundation of China; Canadian Light Source; U.S. Department of Energy","keywords":"Halide; Fast ion conductor; Chemical bond; Electrolyte; Solid-state; Materials science; Chemical physics; Chemistry; Inorganic chemistry; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005081428,0.000121456,0.0001290176,0.0001429488,0.00001744263,0.0000418725,0.0001648626,0.00008311595,0.000100975],"category_scores_gemma":[0.00005092332,0.0001278924,0.00003575031,0.0001309711,0.00003776498,0.0002365671,0.00004009624,0.0001400545,0.0000162385],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001768055,"about_ca_system_score_gemma":0.00001017066,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006284147,"about_ca_topic_score_gemma":0.000006565758,"domain_scores_codex":[0.9993354,0.000002006066,0.0002201499,0.000156155,0.000105619,0.0001806866],"domain_scores_gemma":[0.9998024,0.00003502854,0.0000215097,0.00008512631,0.0000407446,0.00001526658],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001566112,0.00002281067,0.0003080304,0.00003420931,0.00002693169,0.000006859743,0.00001955619,0.0003801334,0.9922315,0.0007347419,0.004929952,0.00128954],"study_design_scores_gemma":[0.0003013908,0.000005977581,0.0004448872,0.00007987906,0.000004005783,0.000005422777,0.00001877372,0.0003230446,0.9800176,0.0147492,0.003934946,0.0001148724],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9840652,0.0002869964,0.004492116,0.0008073892,0.001219296,0.0001000839,0.00005253392,0.0004424318,0.008533903],"genre_scores_gemma":[0.9985231,0.000427371,0.0003754564,0.0001027107,0.0001702785,0.00006718167,0.0001242493,0.00001310107,0.000196607],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01445779,"threshold_uncertainty_score":0.52153,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005293933753843554,"score_gpt":0.2384903820746255,"score_spread":0.233196448320782,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}