{"id":"W4410983790","doi":"10.1002/slct.202502031","title":"Facile Synthesis of Isomeric Hexacyanopyidine Triphenylene Derivatives","year":2025,"lang":"en","type":"article","venue":"ChemistrySelect","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Trois-Rivières","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds de recherche du Québec – Nature et technologies; Université de Montréal; Centre québécois sur les matériaux fonctionnels; Ministère des relations internationales et de la Francophonie; Université du Québec à Trois-Rivières","keywords":"Triphenylene; Chemistry; Combinatorial chemistry; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009622736,0.0001795511,0.000317198,0.00003927831,0.00005070344,0.00001167235,0.0002683519,0.0001369277,0.0001655428],"category_scores_gemma":[0.0006608253,0.0001665296,0.0002233211,0.0003779183,0.0001154971,0.000002272792,0.00009325196,0.00006503987,0.000003124829],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001889352,"about_ca_system_score_gemma":0.00007786608,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001096824,"about_ca_topic_score_gemma":0.000001178223,"domain_scores_codex":[0.9989934,0.00002311231,0.0002902173,0.0003632017,0.0001079567,0.0002220982],"domain_scores_gemma":[0.9993041,0.00006166519,0.0001077113,0.0003755666,0.0000951505,0.00005587327],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004689259,0.00009267659,0.001865343,0.00008871897,0.0001974599,4.091619e-7,0.000004745547,0.000006118123,0.9889827,0.0000112932,0.001951678,0.006752015],"study_design_scores_gemma":[0.0001868314,0.00002046546,0.0003644576,0.00004121863,0.00007257223,0.000001446877,0.00003982545,0.00002710806,0.9879853,0.00005088124,0.01105179,0.0001581189],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9836102,0.001468187,0.001130073,0.0001631301,0.00002037983,0.00006245098,0.00002737743,0.00001682803,0.01350137],"genre_scores_gemma":[0.9965641,0.000287288,0.0003978533,0.00006602674,0.00006449526,0.00003498495,0.00004965175,0.00001237659,0.002523246],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01295388,"threshold_uncertainty_score":0.6790879,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004200038624710758,"score_gpt":0.2328117962120419,"score_spread":0.2286117575873312,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}