{"id":"W4410985825","doi":"10.1002/anie.202505408","title":"A Cobotic, Digitally Controlled Schlenk‐line Unlocks Access to Elusive Lewis‐Base Stabilised Copper Bis(Disilylamides)","year":2025,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Engineering and Physical Sciences Research Council; Royal Society; University of Glasgow; University of Guelph","keywords":"Copper; Lewis acids and bases; Base (topology); Line (geometry); Chemistry; Polymer chemistry; Organic chemistry; Geometry; Mathematics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000250773,0.0003853079,0.0002039494,0.0002962495,0.0002110514,0.0003152848,0.0004386157,0.0002831303,0.001508634],"category_scores_gemma":[0.0003082452,0.0002266666,0.0001197707,0.0001781,0.000416078,0.0003888061,0.0004769651,0.0005009598,0.0007680078],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003387769,"about_ca_system_score_gemma":0.0003045117,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003171367,"about_ca_topic_score_gemma":0.0008282461,"domain_scores_codex":[0.9997835,0.00002403538,0.00001520621,0.0000691359,0.00006763956,0.0000404526],"domain_scores_gemma":[0.9998005,0.0000361455,0.00008511121,0.00003038008,0.00001700819,0.00003085527],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001339491,0.0000277652,0.0001571662,0.00007994414,0.000004859358,0.00009920954,0.00007566671,0.0002203583,0.9911481,0.0008485507,0.0002856958,0.006918616],"study_design_scores_gemma":[0.00001404654,0.0001893809,0.0002704394,0.000003879991,0.000003439994,0.00009856341,0.00001216118,0.001045738,0.9941021,0.0000553378,0.004196386,0.000008580181],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9455612,0.001195408,0.04310187,0.0002366225,0.00008286134,0.0001037457,0.0004220316,0.001570755,0.007725441],"genre_scores_gemma":[0.975396,0.0004600101,0.01839244,0.0001091542,0.00003378164,0.00005931843,0.0002337212,0.0001089549,0.005206556],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001508634,"threshold_uncertainty_score":0.005046844,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01904576875395822,"score_gpt":0.3173332290659305,"score_spread":0.2982874603119723,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}