{"id":"W4411257847","doi":"10.1039/d5ob00813a","title":"Selective monophosphorylation of cyclic diols and polyols <i>via</i> hemiboronic acid catalysis","year":2025,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Catalysis; Chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009967697,0.0002895606,0.0001262922,0.00009184024,0.00009356871,0.0001882839,0.0001961265,0.0001779693,0.001447303],"category_scores_gemma":[0.0001237418,0.00009077279,0.0001820846,0.0000859068,0.0001750315,0.0003552001,0.0002673316,0.000330035,0.0003454004],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001967981,"about_ca_system_score_gemma":0.0001928151,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002877045,"about_ca_topic_score_gemma":0.0006672767,"domain_scores_codex":[0.9999532,0.000005677001,0.000002478632,0.00001187872,0.000010683,0.00001600947],"domain_scores_gemma":[0.9999667,0.000009965522,0.00001250231,0.000003156228,0.000003052756,0.000004521411],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000163217,0.0000847105,0.0004883016,0.0005931185,0.00002552636,0.00022978,0.0000626082,0.005833586,0.9671367,0.007222341,0.0003476245,0.01781243],"study_design_scores_gemma":[0.00002154393,0.0003875189,0.000525851,0.00001036742,0.00001274666,0.0001368817,0.0000277429,0.01156439,0.9803911,0.0009808497,0.005926862,0.00001419681],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9621308,0.00249569,0.02477176,0.0001329328,0.00005126364,0.00007455701,0.0002559799,0.0001597961,0.009927245],"genre_scores_gemma":[0.9922576,0.001296625,0.005162382,0.00002877566,0.000008049338,0.00002687702,0.0001037466,0.00001947702,0.001096554],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001447303,"threshold_uncertainty_score":0.004841685,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.002209572697460261,"score_gpt":0.1927203165609273,"score_spread":0.1905107438634671,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}