{"id":"W4411405924","doi":"10.1149/1945-7111/ade5ce","title":"Enantioselective Electrochemical Detection of Tyrosine Isomers Using Chiral Crown Ether–Modified MWCNTs Electrodes","year":2025,"lang":"en","type":"article","venue":"Journal of The Electrochemical Society","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"King Saud University","keywords":"Chemistry; Electrochemistry; Enantiomer; Selectivity; Differential pulse voltammetry; Electrochemical gas sensor; Cyclic voltammetry; Enantioselective synthesis; Electrode; Stereochemistry; Organic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003267272,0.0002914652,0.0005098986,0.00007332009,0.0002280922,0.00003672141,0.0004778647,0.0004178728,0.00003790917],"category_scores_gemma":[0.0003395622,0.0002191616,0.00107078,0.0008498817,0.0001794237,0.0001181554,0.00008071942,0.001332708,4.493967e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000654458,"about_ca_system_score_gemma":0.0002713777,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000139586,"about_ca_topic_score_gemma":0.000002137225,"domain_scores_codex":[0.9978196,0.00007807937,0.0007651237,0.0002911564,0.0005155126,0.000530534],"domain_scores_gemma":[0.9982827,0.0001130219,0.0007720484,0.00029448,0.0004479767,0.00008982055],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000527146,0.0001550225,0.0001136152,0.00007584837,0.0004155147,5.181017e-7,0.00009705652,0.00001223123,0.9975545,0.00008504433,0.0001113044,0.0008521965],"study_design_scores_gemma":[0.000974663,0.0001097361,0.00008240357,0.0001306053,0.0002495542,0.0001064924,0.0000615553,0.00221875,0.9934465,0.002062371,0.0003649141,0.0001924208],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9384696,0.00118363,0.05928754,0.0002275665,0.0001650379,0.00009570335,0.000001579484,0.00002859586,0.0005407542],"genre_scores_gemma":[0.9969513,0.0001484384,0.001937282,0.0001835287,0.000288127,0.000003279146,0.000001626769,0.00003130505,0.0004550682],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05848175,"threshold_uncertainty_score":0.8937152,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007412508072014612,"score_gpt":0.2409167042724263,"score_spread":0.2335041962004117,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}