{"id":"W4411456892","doi":"10.1002/pol.20250228","title":"Self‐Immolative Polycarbamates From 4‐Hydroxybenzaldehyde, Vanillin, and Syringaldehyde","year":2025,"lang":"en","type":"article","venue":"Journal of Polymer Science","topic":"Polymer composites and self-healing","field":"Materials Science","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Syringaldehyde; Vanillin; Depolymerization; Lignin; Chemistry; Alcohol; Monomer; Organic chemistry; Polymer; Polymerization; Reactivity (psychology)","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002197299,0.000376825,0.0001356527,0.0002464062,0.00008659778,0.0002556788,0.0002206489,0.0002440061,0.0009496844],"category_scores_gemma":[0.0002282434,0.0001474581,0.0002599127,0.0001867548,0.0001964387,0.0003463133,0.0002071028,0.0004415161,0.0003008477],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001755128,"about_ca_system_score_gemma":0.0001807859,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002505854,"about_ca_topic_score_gemma":0.0005349126,"domain_scores_codex":[0.9998322,0.00003168265,0.00001632227,0.00003333659,0.00004880777,0.0000377399],"domain_scores_gemma":[0.9998072,0.00003132178,0.00006229596,0.00002107428,0.00002802251,0.00005007516],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003998923,0.00002375535,0.00005713129,0.00006334559,0.000005679668,0.00003951083,0.00001345869,0.0001158247,0.997268,0.0001992749,0.00002319362,0.002150954],"study_design_scores_gemma":[0.000007690069,0.0002478166,0.0004034241,0.000004163526,0.000007333535,0.00004528747,0.00000469374,0.0003293435,0.997174,0.00001655014,0.001756002,0.000003638987],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9851482,0.001393356,0.008933606,0.00005969984,0.00005371718,0.00006139147,0.0001241401,0.00009638085,0.004129561],"genre_scores_gemma":[0.9897745,0.0009140708,0.006515761,0.00003560493,0.000015036,0.00003874718,0.0002407608,0.00003560541,0.002430039],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009496844,"threshold_uncertainty_score":0.003176987,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005016398091657744,"score_gpt":0.2429386997859838,"score_spread":0.2379223016943261,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}