{"id":"W4411456892","doi":"10.1002/pol.20250228","title":"Self‐Immolative Polycarbamates From 4‐Hydroxybenzaldehyde, Vanillin, and Syringaldehyde","year":2025,"lang":"en","type":"article","venue":"Journal of Polymer Science","topic":"Polymer composites and self-healing","field":"Materials Science","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Syringaldehyde; Vanillin; Depolymerization; Lignin; Chemistry; Alcohol; Monomer; Organic chemistry; Polymer; Polymerization; Reactivity (psychology)","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000987932,0.0002047208,0.0004119282,0.0004219284,0.0004627537,0.0003971285,0.0008880551,0.00006593937,0.00007224942],"category_scores_gemma":[0.00009835861,0.0001625205,0.00008474418,0.0007419536,0.0004552574,0.0009734025,0.0002931267,0.000238366,0.00001244455],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009875424,"about_ca_system_score_gemma":0.0004545715,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002758954,"about_ca_topic_score_gemma":0.000009279151,"domain_scores_codex":[0.9978284,0.00007577147,0.0006859121,0.0003687526,0.0005599089,0.0004812017],"domain_scores_gemma":[0.9985166,0.0002517806,0.0004701339,0.0002842135,0.0002160027,0.0002613113],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002967351,0.00006156343,0.002862662,0.0000147247,0.00002776384,0.00001574567,0.001143732,0.00001134764,0.9927911,0.002363335,0.00006977446,0.0006085514],"study_design_scores_gemma":[0.0004487565,0.0001110359,0.003586347,0.0001067219,0.0001161719,0.00005168415,0.0002685556,0.002107881,0.9912358,0.001432735,0.0003412901,0.0001930369],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9679401,0.02581013,0.002361766,0.0008896287,0.001247997,0.00007571645,0.00001433015,0.00004841062,0.001611946],"genre_scores_gemma":[0.9914026,0.0001355901,0.007468823,0.0006652844,0.000143442,0.000001301686,2.632411e-7,0.000009629615,0.0001730319],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02567454,"threshold_uncertainty_score":0.6627395,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005016398091657744,"score_gpt":0.2429386997859838,"score_spread":0.2379223016943261,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}