{"id":"W4411490149","doi":"10.1021/acscatal.5c01633","title":"Thermochemical and Kinetic Correlations of Redox and Lewis Sites on Cobalt–Molybdenum Oxides: Illustrated with Alkanol-O<sub>2</sub> Catalysis","year":2025,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Catalysis and Oxidation Reactions","field":"Chemical Engineering","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; University of Toronto; Suncor Energy Incorporated","keywords":"Catalysis; Cobalt; Molybdenum; Redox; Kinetic energy; Chemistry; Inorganic chemistry; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001001256,0.0002566798,0.0004527005,0.0003533949,0.000131492,0.00004839939,0.0001398745,0.0001599615,0.00003019168],"category_scores_gemma":[0.000201925,0.0002262686,0.0001081394,0.001298772,0.0002209972,0.0001400574,0.00008361655,0.0002325101,0.00001151789],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006140204,"about_ca_system_score_gemma":0.00003840531,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002020617,"about_ca_topic_score_gemma":0.0001083403,"domain_scores_codex":[0.9986289,0.00002063629,0.0004301167,0.0004586215,0.0002373496,0.0002244284],"domain_scores_gemma":[0.9987261,0.0003239794,0.0001580515,0.0005190963,0.000157696,0.0001150843],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003690442,0.0001148679,0.002047381,0.00005229094,0.0005630002,0.000003134614,0.0001719154,0.0008968309,0.992608,0.0007963699,0.000330723,0.002378654],"study_design_scores_gemma":[0.000566492,0.00003724232,0.005193979,0.00009817314,0.001117949,0.00001172592,0.0003091052,0.003500853,0.9886575,0.00006565399,0.0001776972,0.0002635687],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.996994,0.0003444095,0.001168006,0.0003164377,0.00001979387,0.0001404958,0.00003792454,0.00008670275,0.000892199],"genre_scores_gemma":[0.9985294,0.0001480916,0.0001101486,0.00006114446,0.00002144971,0.00003645008,0.0007469959,0.00002373408,0.0003226332],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003950367,"threshold_uncertainty_score":0.9226966,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005956519651254904,"score_gpt":0.2099889511414801,"score_spread":0.2040324314902252,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}