{"id":"W4411648920","doi":"10.1002/anie.202508224","title":"Titanium–Polyoxometalate Crosslinked Metallo–Supramolecular Polymer as Artificial Interfacial Layer for Highly Persistent and Low–Temperature Tolerant Lithium Metal Batteries","year":2025,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Advanced Battery Materials and Technologies","field":"Engineering","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"Government of Jiangsu Province; Natural Science Foundation of Jiangsu Province; National Natural Science Foundation of China","keywords":"Materials science; Lithium (medication); Polyoxometalate; Chemical engineering; Anode; Polymer; Electrolyte; Titanium; Metal; Nanotechnology; Biointerface; Electrochemistry; Electrode; Composite material; Chemistry; Organic chemistry; Metallurgy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008031964,0.0002429104,0.0002534572,0.0001599184,0.0001041451,0.00016171,0.0001682607,0.000191072,0.000121235],"category_scores_gemma":[0.00005753306,0.0002305369,0.0001494971,0.000101445,0.0001130849,0.0003610312,0.00007937323,0.0001561095,0.00001138644],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007923799,"about_ca_system_score_gemma":0.00001611387,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001016978,"about_ca_topic_score_gemma":0.000006539401,"domain_scores_codex":[0.998998,0.000008159893,0.0003059878,0.0002927948,0.0001736349,0.0002214341],"domain_scores_gemma":[0.9996115,0.00004039379,0.00005405648,0.0001407926,0.0001166563,0.0000366157],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009659259,0.0000303077,0.000007004301,0.00008233366,0.0003347784,0.000004753137,0.00006669191,0.0001388897,0.9952937,0.002390874,0.001117614,0.000436412],"study_design_scores_gemma":[0.0003942222,0.00005083988,0.00008256414,0.00007994607,0.00008370214,0.000009809217,0.0001267846,0.000235011,0.9853859,0.001866007,0.01146111,0.0002241263],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.983313,0.0008210187,0.006414782,0.002301678,0.005006066,0.0002905536,0.0003431547,0.0003903554,0.001119405],"genre_scores_gemma":[0.997513,0.00009497616,0.0003076873,0.0003119795,0.0005336942,0.0001388063,0.0003541747,0.00002873164,0.0007169476],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01420002,"threshold_uncertainty_score":0.9401022,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009894914641666525,"score_gpt":0.2422183065370344,"score_spread":0.2323233918953679,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}