{"id":"W4411648920","doi":"10.1002/anie.202508224","title":"Titanium–Polyoxometalate Crosslinked Metallo–Supramolecular Polymer as Artificial Interfacial Layer for Highly Persistent and Low–Temperature Tolerant Lithium Metal Batteries","year":2025,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Advanced Battery Materials and Technologies","field":"Engineering","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"Government of Jiangsu Province; Natural Science Foundation of Jiangsu Province; National Natural Science Foundation of China","keywords":"Materials science; Lithium (medication); Polyoxometalate; Chemical engineering; Anode; Polymer; Electrolyte; Titanium; Metal; Nanotechnology; Biointerface; Electrochemistry; Electrode; Composite material; Chemistry; Organic chemistry; Metallurgy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000636712,0.0002749426,0.00011065,0.0001641449,0.00007730642,0.0001858129,0.000182663,0.000184359,0.0008734317],"category_scores_gemma":[0.00009097096,0.0001181011,0.0001676029,0.0001117747,0.0001150309,0.0002280416,0.0002146293,0.0002628714,0.0002792139],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001467606,"about_ca_system_score_gemma":0.00009056519,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001090879,"about_ca_topic_score_gemma":0.0002065694,"domain_scores_codex":[0.9999548,0.000004241298,0.00000391805,0.00001162696,0.0000133477,0.00001204164],"domain_scores_gemma":[0.9999533,0.00000443629,0.00001789643,0.000004822495,0.000006074506,0.00001347358],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001642845,0.000009608371,0.00004764595,0.0000337134,0.000004284465,0.00002504598,0.00000607975,0.0001079152,0.9984552,0.00008259936,0.00003856545,0.001173011],"study_design_scores_gemma":[0.000007994404,0.0001095991,0.0007580403,0.000003301342,0.00001391028,0.00005471093,0.000007933847,0.0019376,0.9955791,0.00002484756,0.001496205,0.000006858791],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9871477,0.001104005,0.008985844,0.00007935002,0.00004613863,0.00002217445,0.0001129508,0.0003329035,0.002168939],"genre_scores_gemma":[0.9960492,0.0003066707,0.002459789,0.00002836139,0.000009169302,0.00001577939,0.00005749081,0.00001523878,0.001058365],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008734317,"threshold_uncertainty_score":0.002921999,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009894914641666525,"score_gpt":0.2422183065370344,"score_spread":0.2323233918953679,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}