{"id":"W4411735547","doi":"10.1021/acs.inorgchem.5c01012","title":"Improving the Singlet Oxygen Photosensitization Activity of Fluorenone-Based Materials","year":2025,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds de recherche du Québec – Nature et technologies; Alliance de recherche numérique du Canada; Université de Sherbrooke","keywords":"Chemistry; Singlet oxygen; Fluorenone; Photochemistry; Singlet state; Oxygen; Organic chemistry; Atomic physics; Excited state; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001293547,0.0003097311,0.0001606685,0.0001551659,0.00009326378,0.0002645913,0.0002756925,0.0001855498,0.0008533509],"category_scores_gemma":[0.0001629128,0.0001101274,0.0001268854,0.0001325552,0.0001201002,0.0002189482,0.0001719989,0.0002517905,0.0002199299],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004023866,"about_ca_system_score_gemma":0.0001981192,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004034623,"about_ca_topic_score_gemma":0.001110693,"domain_scores_codex":[0.9999197,0.00001084953,0.00000763591,0.00002009535,0.00001924316,0.0000225667],"domain_scores_gemma":[0.999947,0.00000978457,0.0000159034,0.000005837147,0.000009291228,0.00001226352],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009557101,0.00005022598,0.0001284466,0.0001048097,0.000005939628,0.00004826455,0.00002562329,0.001205456,0.991364,0.0003777035,0.00008765041,0.006506352],"study_design_scores_gemma":[0.00002340275,0.000554304,0.0004765895,0.000008328416,0.00001047471,0.00005764028,0.0000129312,0.002960488,0.9932951,0.00003088161,0.002561878,0.000007890225],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9941749,0.0008647987,0.002443916,0.00004193137,0.000009950687,0.00002952117,0.00006920603,0.00008366882,0.002282122],"genre_scores_gemma":[0.9944333,0.0005318007,0.003903261,0.00001818229,0.000004211769,0.0000224822,0.0000891547,0.00001308512,0.0009845489],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008533509,"threshold_uncertainty_score":0.002919555,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007001394449514023,"score_gpt":0.2161298990688338,"score_spread":0.2091285046193198,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}