{"id":"W4412097964","doi":"10.1039/d5se00423c","title":"Effect of ancillary ligand substitution on photocatalytic hydrogen production","year":2025,"lang":"en","type":"article","venue":"Sustainable Energy & Fuels","topic":"Advanced Photocatalysis Techniques","field":"Energy","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds de recherche du Québec – Nature et technologies; Wallonie-Bruxelles International; Université de Montréal; Council of Scientific and Industrial Research, India; Science and Engineering Research Board; Royal Society of Chemistry","keywords":"Substitution (logic); Hydrogen production; Photocatalysis; Production (economics); Ligand (biochemistry); Hydrogen; Chemistry; Materials science; Photochemistry; Catalysis; Computer science; Economics; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004876783,0.0003433927,0.0004997755,0.0005397101,0.0001958247,0.00002109704,0.0003066702,0.0001998191,0.00002232381],"category_scores_gemma":[0.0004871334,0.0003165918,0.000181871,0.001297067,0.0001775636,0.0003177479,0.0001231955,0.000167341,0.00001026517],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005129159,"about_ca_system_score_gemma":0.0001692815,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001276975,"about_ca_topic_score_gemma":0.00006338549,"domain_scores_codex":[0.9979423,0.0001445867,0.0004460982,0.0006103709,0.0003140485,0.0005425485],"domain_scores_gemma":[0.9983605,0.0001628758,0.0001955703,0.0009392405,0.0002719049,0.00006993897],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001747826,0.0003586155,0.0002575383,0.001742507,0.0003760053,0.000136435,0.0001705379,0.03170554,0.5967266,0.337001,0.001213706,0.02856376],"study_design_scores_gemma":[0.0004191607,0.000450046,0.00001666129,0.0001200473,0.0001065457,0.000004927125,0.0001002627,0.00007167638,0.9337871,0.01640764,0.04828709,0.0002288577],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9516184,0.001264235,0.0009558881,0.00006750847,0.0001962445,0.0008001243,0.000002711446,0.0004437873,0.04465112],"genre_scores_gemma":[0.9789479,0.0001299001,0.00006054953,0.00008787243,0.00008990517,0.0004854529,0.00008134646,0.00003991877,0.02007718],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3370605,"threshold_uncertainty_score":0.9999286,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004459272019581398,"score_gpt":0.2508871157049675,"score_spread":0.2464278436853861,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}