{"id":"W4412139627","doi":"10.1002/adma.202507459","title":"Revisiting the Impact of Anion Selection on Sulfur Redox Reaction Kinetics for High Sulfur Loading Lithium–Sulfur Batteries","year":2025,"lang":"en","type":"article","venue":"Advanced Materials","topic":"Advanced Battery Materials and Technologies","field":"Engineering","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Canada First Research Excellence Fund; University of Alberta","keywords":"Sulfur; Redox; Kinetics; Materials science; Lithium (medication); Ion; Inorganic chemistry; Polysulfide; Lithium–sulfur battery; Electrochemistry; Chemistry; Electrode; Organic chemistry; Electrolyte; Metallurgy; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003177525,0.0003149783,0.0004860563,0.0001642645,0.000145165,0.00008675596,0.0001989886,0.000154218,0.00003054242],"category_scores_gemma":[0.0003138621,0.0002394611,0.00008515754,0.0002738279,0.00006229611,0.0003011986,0.00005539714,0.0001066305,0.00000442844],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002548846,"about_ca_system_score_gemma":0.00001908707,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003416543,"about_ca_topic_score_gemma":0.000002579248,"domain_scores_codex":[0.9985478,0.00004833776,0.0006057008,0.0002924413,0.0001315299,0.0003741837],"domain_scores_gemma":[0.9990024,0.0002188402,0.0002359947,0.0003600117,0.0001607973,0.00002194021],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001997574,0.00001288128,0.00002497449,0.0003127498,0.00005473827,6.277947e-7,0.00002889967,0.007648259,0.9816921,0.002092261,0.0002541646,0.007678623],"study_design_scores_gemma":[0.0004218319,0.0002166544,0.002439008,0.000393198,0.00003304829,0.000005416647,0.00008152256,0.00005275894,0.9889335,0.006112219,0.00108794,0.0002229061],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9883611,0.0001060983,0.00842394,0.0002265214,0.0012752,0.0006067839,0.0001519425,0.0006006511,0.0002477132],"genre_scores_gemma":[0.9962217,0.0002678872,0.002845562,0.00002780211,0.0002702599,0.000159016,0.00005671953,0.00005723958,0.00009386075],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007860505,"threshold_uncertainty_score":0.9764938,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009277328874236646,"score_gpt":0.262169028922487,"score_spread":0.2528917000482503,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}