{"id":"W4412382962","doi":"10.26434/chemrxiv-2024-4gs2l-v2","title":"Nitro and nitritosilanes: Do they and can they exist?","year":2025,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Ammonia Synthesis and Nitrogen Reduction","field":"Chemical Engineering","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"National Research Council Canada; Natural Sciences and Engineering Research Council of Canada; Université Laval","keywords":"Nitro; Computer science; Political science; Chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001419739,0.0003675055,0.0004570429,0.0001032557,0.00008552516,0.0000945546,0.000201968,0.0004260334,0.00001776959],"category_scores_gemma":[0.0001069571,0.0003366356,0.0001057795,0.00004512079,0.00006510763,0.00003194034,0.0004324434,0.0005984972,0.000004517874],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006869483,"about_ca_system_score_gemma":0.00005571669,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004411547,"about_ca_topic_score_gemma":0.00003711849,"domain_scores_codex":[0.9986894,0.00002615837,0.0002781008,0.0005806125,0.0001475703,0.0002781533],"domain_scores_gemma":[0.9991398,0.0001239287,0.0001014149,0.0004457519,0.00005130062,0.0001377741],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004294981,0.0005600532,0.02378802,0.011076,0.002587338,0.00009578498,0.00957719,0.0007877641,0.8276644,0.03587898,0.003913492,0.08364151],"study_design_scores_gemma":[0.001296914,0.00004319396,0.001897248,0.002308819,0.0008108648,0.00009769775,0.001306079,0.001764512,0.9126493,0.06867123,0.00680532,0.002348823],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9811729,0.005209742,0.0000399447,0.0004295923,0.0003192252,0.0002687599,0.00003633479,0.0002036994,0.01231978],"genre_scores_gemma":[0.9967312,0.001032352,0.0007064167,0.0000383083,0.0003754829,0.00008107317,0.00003596938,0.00003776606,0.000961474],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08498492,"threshold_uncertainty_score":0.9999086,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01464182526395954,"score_gpt":0.2346361194913914,"score_spread":0.2199942942274319,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}