{"id":"W4412561244","doi":"10.1021/jacs.5c05168","title":"Chiroptical Signal Amplification in Amorphous Siloxane Network by Asymmetric Ring Distortion","year":2025,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Photoreceptor and optogenetics research","field":"Neuroscience","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Nautical Research Society","funders":"Université de Bordeaux; Japan Society for the Promotion of Science; Centre National de la Recherche Scientifique; Agence Nationale de la Recherche","keywords":"Chemistry; Siloxane; Distortion (music); Amorphous solid; SIGNAL (programming language); Ring (chemistry); Nanotechnology; Optoelectronics; Crystallography; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004985335,0.000147641,0.00005890932,0.00008794796,0.00009376396,0.000124163,0.0001170183,0.0001165353,0.0008733195],"category_scores_gemma":[0.0001194628,0.00008769973,0.00007843348,0.00007528244,0.0002346107,0.0002153026,0.0001343618,0.00019567,0.0001182065],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001018542,"about_ca_system_score_gemma":0.00006577319,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001948651,"about_ca_topic_score_gemma":0.0003457755,"domain_scores_codex":[0.9999616,0.000003734497,0.000001674341,0.00001101809,0.00001180545,0.00001022018],"domain_scores_gemma":[0.9999304,0.00002619167,0.00002417797,0.000005328657,0.000007447476,0.000006543867],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002414318,0.000005836751,0.0001579267,0.0000293626,0.00000204345,0.00006779587,0.00003153435,0.000273566,0.9977027,0.0003579453,0.00003643137,0.001310878],"study_design_scores_gemma":[0.000005741083,0.0001085343,0.001210794,0.000003821739,0.000003000719,0.00007704448,0.00003639337,0.005186798,0.9925008,0.0001779986,0.000684592,0.000004525371],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9944582,0.0002790096,0.002905096,0.00004278367,0.00001145948,0.000007486527,0.00004621489,0.00003026038,0.002219409],"genre_scores_gemma":[0.9981224,0.0001465014,0.00131289,0.00001743613,0.000004161956,0.000004428952,0.0000259487,0.00000330259,0.0003628706],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008733195,"threshold_uncertainty_score":0.002921581,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.017838065102768,"score_gpt":0.298309407019221,"score_spread":0.2804713419164531,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}