{"id":"W4412561244","doi":"10.1021/jacs.5c05168","title":"Chiroptical Signal Amplification in Amorphous Siloxane Network by Asymmetric Ring Distortion","year":2025,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Photoreceptor and optogenetics research","field":"Neuroscience","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Nautical Research Society","funders":"Université de Bordeaux; Japan Society for the Promotion of Science; Centre National de la Recherche Scientifique; Agence Nationale de la Recherche","keywords":"Chemistry; Siloxane; Distortion (music); Amorphous solid; SIGNAL (programming language); Ring (chemistry); Nanotechnology; Optoelectronics; Crystallography; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000409238,0.0001080952,0.0002497114,0.00004504051,0.000103777,0.00004470877,0.0005922629,0.00005057901,0.00001377008],"category_scores_gemma":[0.0005186967,0.0000772592,0.0002810595,0.001795641,0.0004283,0.00005879113,0.0001487823,0.0006625125,0.000002762753],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004143788,"about_ca_system_score_gemma":0.0000893836,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002549206,"about_ca_topic_score_gemma":4.103142e-7,"domain_scores_codex":[0.9984132,0.0001351883,0.0004041194,0.0001958176,0.0005240723,0.0003276033],"domain_scores_gemma":[0.9989331,0.0004115984,0.000327071,0.0001750173,0.00005549277,0.00009775448],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007078381,0.0001282199,0.006281549,0.000006235428,0.000009623182,9.519998e-7,0.00004208478,0.0002791251,0.9778584,0.00002672744,0.01047781,0.004818531],"study_design_scores_gemma":[0.0003400828,0.00005702828,0.01126455,0.00003238187,0.00001554591,0.00001030329,0.00004113575,0.002147941,0.9837429,0.000340808,0.001911358,0.00009594289],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957972,0.0001361128,0.002454772,0.000871064,0.0001531021,0.00009683042,0.000003971526,0.000008458893,0.0004784467],"genre_scores_gemma":[0.9981418,0.0002211969,0.0006065436,0.0007944462,0.0001471829,0.000004116897,6.095854e-7,0.000009675987,0.00007438394],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008566449,"threshold_uncertainty_score":0.3150539,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.017838065102768,"score_gpt":0.298309407019221,"score_spread":0.2804713419164531,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}