{"id":"W4412632247","doi":"10.1021/acselectrochem.5c00210","title":"The Crucial Role of Rotation Speed on the Determination of Tafel Slopes of Electrocatalysts in Rotating Disk Electrode Experiments","year":2025,"lang":"en","type":"article","venue":"ACS electrochemistry.","topic":"Electrocatalysts for Energy Conversion","field":"Energy","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Max-Planck-Gesellschaft; Deutscher Akademischer Austauschdienst; Deutsche Forschungsgemeinschaft; Fonds der Chemischen Industrie","keywords":"Tafel equation; Electrode; Rotation (mathematics); Rotational speed; Rotating disk electrode; Materials science; Chemistry; Physics; Geometry; Electrochemistry; Mathematics; Classical mechanics; Physical chemistry; Cyclic voltammetry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005267096,0.0002587498,0.0003665987,0.0001597412,0.0001538026,0.00001745742,0.0006801262,0.0001494164,0.00001040801],"category_scores_gemma":[0.000839483,0.0001955424,0.000136957,0.0009910243,0.0001357695,0.0001060076,0.00007491383,0.0003036108,0.000001298048],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002480548,"about_ca_system_score_gemma":0.0002651603,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004427732,"about_ca_topic_score_gemma":0.0004184939,"domain_scores_codex":[0.9977043,0.0001305078,0.0007817021,0.0003494862,0.0005523111,0.0004816977],"domain_scores_gemma":[0.9978712,0.0006143491,0.0006223731,0.0005496276,0.0003133889,0.00002906445],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003491526,0.0001170898,0.0003026049,0.00004530606,0.00007474017,4.339716e-7,0.0003077456,0.00007840826,0.9630852,0.01495595,0.00002362569,0.02065974],"study_design_scores_gemma":[0.0005784685,0.0002015963,0.0002932243,0.0001170083,0.00004429306,0.000001879748,0.0002738535,0.001199204,0.9916508,0.005298689,0.0001977858,0.0001431736],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.989898,0.0006797233,0.0001974987,0.0001795874,0.00003157985,0.0002613056,9.408238e-7,0.00002405149,0.008727261],"genre_scores_gemma":[0.9991508,0.00009925433,0.0001202356,0.00003272451,0.00003437619,0.00005755192,0.00004719842,0.00002582669,0.0004320453],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02856562,"threshold_uncertainty_score":0.7973987,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005242175558109029,"score_gpt":0.2408148945682906,"score_spread":0.2355727190101816,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}