{"id":"W4412632247","doi":"10.1021/acselectrochem.5c00210","title":"The Crucial Role of Rotation Speed on the Determination of Tafel Slopes of Electrocatalysts in Rotating Disk Electrode Experiments","year":2025,"lang":"en","type":"article","venue":"ACS electrochemistry.","topic":"Electrocatalysts for Energy Conversion","field":"Energy","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Max-Planck-Gesellschaft; Deutscher Akademischer Austauschdienst; Deutsche Forschungsgemeinschaft; Fonds der Chemischen Industrie","keywords":"Tafel equation; Electrode; Rotation (mathematics); Rotational speed; Rotating disk electrode; Materials science; Chemistry; Physics; Geometry; Electrochemistry; Mathematics; Classical mechanics; Physical chemistry; Cyclic voltammetry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.004182329,0.001755573,0.001016346,0.001041797,0.0003738514,0.001733252,0.001117553,0.001217067,0.001847501],"category_scores_gemma":[0.01387875,0.0007432487,0.000545927,0.000999955,0.0009812803,0.001940341,0.0007931344,0.002391169,0.001384251],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003480605,"about_ca_system_score_gemma":0.0004120297,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003388433,"about_ca_topic_score_gemma":0.0005130531,"domain_scores_codex":[0.9955435,0.001139875,0.0004764924,0.001078424,0.001478985,0.0002826753],"domain_scores_gemma":[0.9927111,0.00457404,0.0007512849,0.0008113644,0.001054403,0.00009780737],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002901471,0.00007585806,0.001613212,0.0007927981,0.00005302999,0.0002556984,0.0003498873,0.0007861624,0.9593367,0.001202125,0.0007059221,0.0345385],"study_design_scores_gemma":[0.00001301909,0.0002605591,0.003833127,0.00008443513,0.00004853115,0.000291658,0.0001621163,0.003200957,0.9858166,0.0005165868,0.005718236,0.00005417842],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.716863,0.01967542,0.2413955,0.002414594,0.002245177,0.000558496,0.001798118,0.002452426,0.01259714],"genre_scores_gemma":[0.8915921,0.01038155,0.09257732,0.0003581368,0.0002384577,0.0004087619,0.0008471573,0.000497476,0.003098912],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004182329,"threshold_uncertainty_score":0.02211851,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005242175558109029,"score_gpt":0.2408148945682906,"score_spread":0.2355727190101816,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}